Solution thermodynamics of tris-(2,4-ditert-butylphenyl)-phosphite in a series of pure solvents

Yang, Jinyue; Hou, Baohong; Huang, Jingjing; Li, Xin; Tian, Beiqian; Wang, Na; Bi, Jingtao; Hao, Hongxun

doi:10.1016/j.molliq.2019.03.122

Cited by 31 publications

(6 citation statements)

References 24 publications

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“…The gravimetric method was used to determine the solubility of 1,5-pentanediamine adipate dihydrate in different binary solvent mixtures [9]. Known mass of solvent and excess 1,5-pentanediamine adipate dihydrate were added to a 100 mL crystallizer.…”

Section: Apparatus and Methodsmentioning

confidence: 99%

Thermodynamic Properties of 1,5-Pentanediamine Adipate Dihydrate in Three Binary Solvent Systems from 278.15 K to 313.15 K

Zhao

Hou

et al. 2022

Crystals

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In this work, solubility data of 1,5-pentanediamine adipate dihydrate in binary solvent systems of water + methanol, water + ethanol and water + N,N-dimethylformamide were experimentally measured via a static gravimetric method in the temperature range from 278.15 K to 313.15 K under atmospheric pressure. The results indicated that the solubility of 1,5-pentanediamine adipate dihydrate increased with the rising of temperature in all the selected binary solvent systems. For water + N,N-dimethylformamide, solubility increased as the mole fraction of water increased. However, the rising tendency changed when the temperature was higher than 303.15 K for water + methanol, and it would show a cosolvency phenomenon for water + ethanol. Furthermore, the solubility data were fitted with modified an Apelblat equation, NRTL model, combined nearly ideal binary solvent/Redlich Kister (CNIBS/R-K) model and Jouban–Acree model. The calculation results agreed well with the experimental data. Finally, the mixing thermodynamic properties of 1,5-pentanediamine adipate dihydrate in all tested solvents were calculated based on the experimental data and NRTL model.

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Section: Apparatus and Methodsmentioning

confidence: 99%

Thermodynamic Properties of 1,5-Pentanediamine Adipate Dihydrate in Three Binary Solvent Systems from 278.15 K to 313.15 K

Zhao

Hou

et al. 2022

Crystals

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“…The gravimetric method was used to determine the solubility of the polyamide 56 salt in water, under the conditions of with/without magnetic field of different intensities . A known mass of deionized water and excessive polyamide 56 salt were added to a 100 mL water-jacketed glass crystallizer.…”

Section: Methodsmentioning

confidence: 99%

“…The gravimetric method was used to determine the solubility of the polyamide 56 salt in water, under the conditions of with/without magnetic field of different intensities. 20 A known mass of deionized water and excessive polyamide 56 salt were added to a 100 mL waterjacketed glass crystallizer. A thermostat (Nanjing Xianou Instrument Manufacturing Co., Ltd., China) with the temperature accuracy of ±0.1 °C was used to keep the system at the specified temperature.…”

Section: Methodsmentioning

confidence: 99%

Mechanistic Study on the Effect of Magnetic Field on the Crystallization of Organic Small Molecules

Zhao

Hou

Liu

et al. 2021

Ind. Eng. Chem. Res.

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Exploring the effect of magnetic field on crystallization process and revealing the mechanism of magnetic field can enrich the regulation and intensification methods of crystallization process. In this paper, the effect of magnetic field on crystal nucleation and growth and its mechanism were comprehensively studied from the perspective of crystallization thermodynamics and kinetics, using a small organic molecule polyamide 56 salt as the model compound. The solubility, nucleation kinetics, and growth kinetics of the polyamide 56 salt were measured in the absence and presence of magnetic field, respectively. It was found that the magnetic field can improve the solubility of the model compound. The introduction of magnetic field can result in solubilization effect and enhance the directional motion of particles which can weaken the solute−solvent interaction. In addition, the introduction of magnetic field will prolong the nucleation induction period, widen the metastable zone width, and increase the nuclear barrier, which is the result of the competition between the directional motion of particles induced by the magnetic field and the inherent random Brownian motion. Moreover, the magnetic field can also effectively affect the crystal morphology and particle size, which is the result of the synergistic effect of nucleation kinetics and growth kinetics.

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“…The enthalpy and entropy of propylparaben during heating and cooling processes in eq can be calculated using the following equations where C p (s) and C p (l) refer to specific heat capacities of propylparaben in the solid form and the liquid form, respectively.…”

Section: Solubility Modelsmentioning

confidence: 99%

Solubility Measurement, Modeling, and Dissolution Thermodynamics of Propylparaben in 12 Pure Solvents

et al. 2020

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The solubility data of propylparaben in polar and apolar solvents were first measured at T = (283.15−323.15) K using the shake flask method. The results show that solubility of propylparaben in all selected solvents increases proportionally with temperature, and at a high temperature (323.15 K), propylparaben is most soluble in acetone, followed by isopropanol, 1-propanol, ethanol, methanol, ethyl acetate, 1-butanol, butyl acetate, methyl acetate, isobutanol, acetonitrile, and water. To mathematically represent the experimentally measured solubility data, the modified Apelblat model, Wilson model, and NRTL model were applied. The difference between experimentally measured and predicted values was described by the percentage of averaged relative deviation. The best correlation of solubility versus temperature with the highest accuracy was obtained using the modified Apelblat model. Dissolution thermodynamics of propylparaben in different solvents at different temperatures were calculated and discussed to study the dissolution mechanism of propylparaben in different solvents.

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Solution thermodynamics of tris-(2,4-ditert-butylphenyl)-phosphite in a series of pure solvents

Cited by 31 publications

References 24 publications

Thermodynamic Properties of 1,5-Pentanediamine Adipate Dihydrate in Three Binary Solvent Systems from 278.15 K to 313.15 K

Thermodynamic Properties of 1,5-Pentanediamine Adipate Dihydrate in Three Binary Solvent Systems from 278.15 K to 313.15 K

Mechanistic Study on the Effect of Magnetic Field on the Crystallization of Organic Small Molecules

Solubility Measurement, Modeling, and Dissolution Thermodynamics of Propylparaben in 12 Pure Solvents

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