1975
DOI: 10.1021/ma60048a024
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Solutions of Flexible Polymers. Neutron Experiments and Interpretation

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Cited by 946 publications
(572 citation statements)
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References 17 publications
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“…Here, the distances rn ) for n ncc are swollen, and the distances r' > for n > ncc are unperturbed, in contrast to the change of behaviour around n,,. Previous calculations [15] (2.12) which was observed in a small-angle neutron scattering experiment [15].…”
mentioning
confidence: 75%
See 1 more Smart Citation
“…Here, the distances rn ) for n ncc are swollen, and the distances r' > for n > ncc are unperturbed, in contrast to the change of behaviour around n,,. Previous calculations [15] (2.12) which was observed in a small-angle neutron scattering experiment [15].…”
mentioning
confidence: 75%
“…In the high concentration range, i.e. for C greater than C*, S(q, c) is a Lorentzian [15] 1 where A is a constant at a given concentration and K is the inverse of the screening length 03BE By reference to this form, the homogeneous function will be where F(x) is the cross-over function. This function is unknown, but behaves asymptotically as…”
mentioning
confidence: 99%
“…Similarly, the mapping of the problem of a polymer in a good solvent (also referred to as self-avoiding walk) to an n-vector spin model with n → 0 established a firm link between the universal behavior of polymers and critical phenomenon, 53 thereby explaining the Flory law for the variation of R g as a function of N , the number of monomers. [54][55][56] More importantly, such a mapping showed why the critical exponents, known in magnetic models, arise in the description of polymer properties, regardless of the chemical details of the monomers.…”
Section: Rationale For Developing Structure-based Cg Modelsmentioning
confidence: 99%
“…The equilibrium aspects of confined polymers are well understood [17,26]. The equilibrium free energy of polymer confined to a sphere is not extensive [27,28] in contrast to polymer localization in a slit or a cylinder.…”
mentioning
confidence: 99%