Solvent‐Assisted Anisotropic Cleavage of Transition Metal Carbide into 2D Nanoflakes

Abstract

Mechanical exfoliation of bulk layered materials into atomic‐layer thin nanosheets has become a general strategy to obtain 2D nanomaterials, which seems intuitively unsuitable for non‐van der Waals crystals. However, a new method is proposed, namely, solvent‐assisted anisotropic cleavage (SAAC), for producing thin nanostructures from transition metal carbides (TMCs), including titanium carbide (TiC) and tungsten carbide (WC). The SAAC method harnesses the intrinsic anisotropic hardness properties of the TMC and enables efficient cleavage of bulk TMC into 2D layers. Under ultrasonication in appropriated solvent, TiC crystals show preferable cleavage along [110] direction and produce 2D nanoflakes. The obtained 2D nanoflakes are successfully applied for ultrafast photonics as saturable absorbers (SAs) in mode‐locked thulium fiber lasers, where stable third‐order harmonically mode‐locked dissipative solitons are realized at 2 μm. The success of the SAAC process opens a new pace toward preparation of 2D nanomaterials.

Two-dimensional nanomaterials: synthesis and applications in photothermal catalysis

“…19–23 Various synthesis methods have been devoted to acquiring 2D nanomaterials, including mechanical exfoliation, liquid exfoliation, chemical vapor deposition (CVD), and wet chemical strategy. 24–26 Therefore, the family of 2D nanomaterials has been dramatically enriched, including single-element 2D-xenes (graphene, silicene, germanene, stanene, phosphorene, tellurene, bismuthine, borophene), 27,28 transition metal dichalcogenides (TMDs), 29 hexagonal boron nitride (h-BN), 30 covalent organic frameworks (COFs), 31 transition metal oxides (TMOs), 32 black phosphorus (BP), 33 transition metal carbides, nitrides and carbonitrides (MXenes), 34 metal–organic frameworks (MOFs), 35 layered double metal hydroxides (LDHs), 36 and two-dimensional metals nanosheets 37 (Fig. 1c).…”

Lead-free double-perovskite Cs4CuSb2Cl12 as an efficient saturable absorber for Q-switched mode-locking fiber lasers

“…12 Our group previously employed 2D materials of bismuthene and transition metal carbides as saturable absorbers for mode-locking Tm-doped fiber lasers and successfully realized 2 μm NIR-wavelength output. 13,14…”