1960
DOI: 10.1021/ja01488a074
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SOLVENT EFFECTS ON MESOMERIC CHARGE SEPARATION1

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Cited by 21 publications
(5 citation statements)
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“…This appears to be important only for systems where solvation either enhances the contribution of resonance of the exalted type, or when the substituent is very prone to protonic solvation (e.g. hydroxyl and amino substituents) (48). Such resonance systems have been excluded and the solvation character of the media in this study does not greatly vary.…”
Section: ~Lfedium Efectsmentioning
confidence: 94%
“…This appears to be important only for systems where solvation either enhances the contribution of resonance of the exalted type, or when the substituent is very prone to protonic solvation (e.g. hydroxyl and amino substituents) (48). Such resonance systems have been excluded and the solvation character of the media in this study does not greatly vary.…”
Section: ~Lfedium Efectsmentioning
confidence: 94%
“…contribute to increasingly greater extents in more ionizing media [364]. It is concluded [363] that ó° values have general utility in identifying and studying specific polarization and Ar-Y resonance effects dependent on both solvent conditions and reaction type, and that deviations from the expression \og(k/k 0 ) = ó°ñ (5.490) measure such effects [362,365].…”
Section: Other ó Valuesmentioning
confidence: 97%
“…The silaindan (6) arises from [o-(trimethylsilyl)phenyl] carbene via a carbene-carbene rearrangement of the (trimethylsilyl)phenylcarbene. 8,9,22 The styrene 5 is probably formed by the thermal decomposition of l,l-dimethyl-2-phenylsilirane (8) produced by the intramolecular C-H insertion of the (trimethylsilyl)phenylcarbene. The siloxane (7) is the addition product of trimethylsilanol to 1,2,2-trimethyl-lphenylsilene (9) and hexamethyldisiloxane (3) is produced by dehydration of trimethylsilanols.…”
Section: Resultsmentioning
confidence: 99%
“…1975, 145. (8) Barton, T. J.; Kilgour, J. A.; Gallucci, R. R.; Rothschild, A. J.; Slutsky, J.; Wolf, A. D.; Jones, M., Jr. J.…”
Section: Introductionunclassified