Solvent induced synthesis, structure and properties of coordination polymers based on 5-hydroxyisophthalic acid as linker and 1,10-phenanthroline as auxiliary ligand

Design and synthesis of coordination polymers with chelated units and their application in nanomaterials science

“…Solvothermal reactions of terphenyl-2,5,2 0 ,5 0 -tetracarboxylic acid (H 4 L) and M(II) in presence of bpy give three CPs with [ML 0.5 (bpy)] n (M ¼ Co, Ni) and [Cu(H 2 L)(bpy)] n units. 161 Of interest are systematic arrays of CPs including bpy chelating ligand and different derivatives of isophthalic acid such as 5-(4 0 -methylphenyl) group (1D linear chain linked with L bridge), 162 OH group (1D zigzag chains linked by H-bonding and p-p stacking interactions to form a 3D supramolecular structure), 163 5-(4-carboxybenzylamino) group (1D, 2D and 3D frameworks), 164 5-(imidazol-1-yl-methyl) group (double-chained and 3D supramolecular structures through H-bond/p-p interactions), 165 4,5-di(3 0 -carboxylphenyl) group (0D, 1D, 2D and 3D structures) etc. 166 Such arrays make it possible to reveal fundamental structure-property relations to dene possible directions of practical applications for CPs.…”

Cobalt(II) and silver(I) coordination polymers containing flexible bis (benzimidazol‐1‐yl)hexane ligands: synthesis, crystal structures, sensing and photocatalytic properties

“…In recent years, design and synthesis of metal coordination polymers (CPs) has become a new frontier for coordination chemistry research due to these CPs exhibiting charming network topologies and potential applications in gas sorption/separation, magnetism, nonlinear optics, catalysis . As we know, the selection suitable N/O‐containing ligands, and metal centers are demonstrated to be the effective way to modulate the structures and properties of CPs.…”