Some Issues of Complex Studies of Phase Equilibria and Thermodynamic Properties in Ternary Chalcogenide Systems Involving Emf Measurements (Review)

Бабанлы, М. Б.; Машадиева, Л. Ф.; Бабанлы, Д. М.; Imamaliyeva, S. Z.; Тагиев, Д. Б.; Yusibov, Yu. A.

doi:10.1134/s0036023619130035

Cited by 59 publications

(30 citation statements)

References 134 publications

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“…The thermodynamic functions of compounds are their fundamental characteristics and, together with phase diagrams, form the basis for the synthesis and growth of crystals, as well as optimizing the development conditions for new materials based on them [10,[16][17][18].…”

Section: Introductionmentioning

confidence: 99%

THERMODYNAMİC PROPERTİES OF THE Bi2Te3 AND Bi4Te5 COMPOUNDS

Hasanova¹,

Dashdiyeva²,

Yusibov³

et al. 2020

Chemical Problems

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The thermodynamic properties of the BiTe system were studied in the 55-65 at% Te compositions interval and temperatures 300-450 K by using the electromotive forces method. Relative partial molar functions of bismuth in the alloys were calculated. Based on the potential-forming reactions for Bi 2 Te 3 and Bi 4 Te 5 compounds, a mutually consistent set of standard thermodynamic functions and standard entropies is obtained. A comparative analysis of the data obtained for Bi 2 Te 3 with literature is performed, for Bi 4 Te 5 thermodynamic functions were obtained for the first time.

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Section: Introductionmentioning

confidence: 99%

THERMODYNAMİC PROPERTİES OF THE Bi2Te3 AND Bi4Te5 COMPOUNDS

Hasanova¹,

Dashdiyeva²,

Yusibov³

et al. 2020

Chemical Problems

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“…Heavy p-elements chalcogenides attract a lot of attention of scientists due to their functional properties, such as thermoelectric, photoelectric, optical, magnetic et al properties [1][2][3][4][5][6][7]. Furthermore, despite the toxicity of thallium, complex thallium chalcogenides are closely monitored as topological insulators [6,8,9], Weyl semimetals [10], photo-, X-ray and gamma radiation detectors [11][12][13], as well as thermoelectric materials [4,14,15].…”

Section: Introductionmentioning

confidence: 99%

PHASE EQUILIBRIA IN THE TlTe-Tl9ErTe6 SYSTEM

Mekhdiyeva¹

2020

AChJ

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“…The development of new multi-component phases of variable compositions requires the study of phase equilibria in systems composed of structural analogs of binary and ternary compounds, since the formation of solid solutions in them is expected [12,26].…”

Section: Introductionmentioning

confidence: 99%

MODELING THE PHASE DIAGRAMS OF THE Tl9SmTe6–Tl4PbTe3 AND Tl9SmTe6–Tl9BiTe6 SYSTEMS

Imamaliyeva¹,

Alakbarzade²,

Mamedov³

et al. 2020

AChJ

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Using the multipurpose genetic algorithm, the analytical models of phase diagrams of the Tl9SmTe6–Tl8Pb2Te6 and Tl9SmTe6–Tl9BiTe6 systems as temperature dependencies of compositions of the equilibrium phases were obtained. The boundaries of the uncertainty band for the liquidus and solidus curves of solid solutions are determined. According to the model of regular solutions of non-molecular compounds, the thermodynamic functions of mixing solid solutions depending on the composition and temperature are determined. It was found that solid solutions based on the Tl9SmTe6, Tl8Pb2Te6 and Tl9BiTe6 compounds are thermodynamically stabile in the whole concentration range

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Some Issues of Complex Studies of Phase Equilibria and Thermodynamic Properties in Ternary Chalcogenide Systems Involving Emf Measurements (Review)

Cited by 59 publications

References 134 publications

THERMODYNAMİC PROPERTİES OF THE Bi2Te3 AND Bi4Te5 COMPOUNDS

THERMODYNAMİC PROPERTİES OF THE Bi2Te3 AND Bi4Te5 COMPOUNDS

PHASE EQUILIBRIA IN THE TlTe-Tl9ErTe6 SYSTEM

MODELING THE PHASE DIAGRAMS OF THE Tl9SmTe6–Tl4PbTe3 AND Tl9SmTe6–Tl9BiTe6 SYSTEMS

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