The study of coprime probabilities and graphs have its own uniqueness that produces a particular pattern according to its variabilities. Some obvious results can be seen from previous research where the domination number will always be equal to one and the types of graphs that can be formed are either star, planar or r-partite graph depending on certain cases. For the probability, the results vary according to the groups and certain cases need to be considered. The noncoprime graph has been introduced and it is defined as a graph associated to the group G with vertex set G\{e} such that it is possible that two separate vertices are adjacent when the orders are relatively noncoprime. However, in probability theory, the study of noncoprime probability of a group has not been introduced yet. Hence, a thorough study has been conducted where the goal of this research is to introduce a newly defined graph and probability which are the prime power noncoprime graph and prime power noncoprime probability of a group. The focus of this approach is that the greatest common divisor of the order of x and y, where x and y are in G, is equal to a power of prime number. In this paper, the scope of the group is mainly focused on some dihedral groups, quasi-dihedral groups, and some generalized quaternion groups. Some invariants, which are the diameter, girth, clique number, chromatic number, domination number, and independence number of prime power noncoprime graph are found. Additionally, the generalization of the prime power noncoprime probability are also obtained.