Spatiotemporal heterogeneity of soil available nitrogen (AN) (sum of NO3−–N and NH4+–N) is the essential basis for soil management and highly correlates to crop yield. Both geostatistical and traditional analyses were used to describe the spatiotemporal distribution of AN in the 0–20‐cm soil depth on typical Mollisol slopes (S1 and S2) in Northeast China. The concentration of NO3−–N dynamics at slope positions was typically opposite to NH4+–N. The peak values of AN typically moved from the summit of the slope to the bottom from spring to autumn and were mainly influenced by the content of NO3−–N (S1, 7·9–18·9 mg kg−1; S2, 1·2–103·6 mg kg−1), both of NO3−–N (S1, 3·9–8·3 mg kg−1; S2, 2·2–28·0 mg kg−1) and NH4+–N (S1, 21·4–30·5 mg kg−1; S2, 2·1–23·3 mg kg−1), and NH4+–N (S1, 10·5–28·9 mg kg−1; S2, 5·0–39·0 mg kg−1) in the seedling stage, vegetative growth stage, and reproductive growth stage, respectively. The spatial autocorrelation of AN was strong and was mainly influenced by structural factors during crop growth stages. This was mainly determined by soil erosion–deposition (SED) and soil temperature–moisture (STM) in the seedling stage; this was also mainly influenced by SED, STM, crop type, and crop growth in the vegetative growth stage and by early STM and early SED in the reproductive growth stage. Generally, the content of AN, NO3−–N, and NH4+–N on the whole slope was mainly determined by the early SED and local fertilizer application, while their spatiotemporal heterogeneity, especially the evenness, was mainly changed by SED, STM, crop growth, and crop types on the slope scale. In order to increase more crop yields, additional N fertilizer application on both the summit and the bottom during the vegetative growth stage and conservation tillage systems or additional soil amendments on the back slopes was necessary. Copyright © 2016 John Wiley & Sons, Ltd.