Speciation of organotin compounds in water and seafood samples by online hyphenation of porous polymer-based magnetism-enhanced in-tube solid phase microextraction and HPLC

Song, Xiaochong; Luo, Qing; Huang, Xiaojia

doi:10.1016/j.aca.2022.340175

Cited by 10 publications

(2 citation statements)

References 31 publications

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“…由于实际样品往往由多种元素的不同形态组成，想要通过单独某一种仪器实现目标元素的形态分析是很困难的。不同的样品处理技术及检测器的联用在元素形态分析中能够起到提高准确性、重现性和可操作性的作用。本文综述了不同的联用技术在元素形态分析中的应用。 2.1 液相色谱联用技术应用于元素形态分析液相色谱是以液体为流动相的高效色谱分析方法，分析速度快，分离效率高，能与不同的分析仪器联用进行更为高效的元素形态分析 [1,2] ，样品无需进行汽化，能用于高沸点及热不稳定化合物的分离，适用范围广。 2.1.1 液相色谱与电感耦合等离子体质谱联用…”

Section: 联用技术在元素形态分析中的应用unclassified

Application of Hyphenated Technique in Element Speciation Analysis

Tang¹,

Shi²,

Du³

et al. 2023

Daxue Huaxue

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This paper investigates the significance of element speciation analysis, the various hyphenated techniques used in element speciation analysis, and their application in real samples. This involves a variety of separation technologies, such as high-performance liquid chromatography, ion chromatography, size exclusion chromatography, gas chromatography, and capillary electrophoresis, as well as various detection methods, such as inductively coupled plasma mass spectrometry, inductively coupled plasma optical emission spectrometry, atomic fluorescence spectrometry, and atomic absorption spectrometry. Based on this, we developed teaching experiments, combined theory with practice, and further strengthened students' understanding, mastery, and application of knowledge.

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Section: 联用技术在元素形态分析中的应用unclassified

Application of Hyphenated Technique in Element Speciation Analysis

Tang¹,

Shi²,

Du³

et al. 2023

Daxue Huaxue

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“…The analytical procedure proposed included ICP-MS measurement of retained species and was applied after validation with CRM for water samples analysis. Solid-phase microextraction was used for the enrichment of organic Sn species prior to HPLC measurement with fluorescent detection [ 82 ]. Magnetic nanoparticles were embedded in a porous polymer matrix in a capillary and utilized as the microextraction column for Sn species enrichment prior to HPLC separation.…”

Section: Polymeric Materials For Solid-phase Extractionmentioning

confidence: 99%

Polymeric Materials in Speciation Analysis Based on Solid-Phase Extraction

Dakova,

Yordanova,

Karadjova

2023

Molecules

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Speciation analysis is a relevant topic since the (eco)toxicity, bioavailability, bio (geo)chemical cycles, and mobility of a given element depend on its chemical forms (oxidation state, organic ligands, etc.). The reliability of analytical results for chemical species of elements depends mostly on the maintaining of their stability during the sample pretreatment step and on the selectivity of further separation step. Solid-phase extraction (SPE) is a matter of choice as the most suitable and widely used procedure for both enrichment of chemical species of elements and their separation. The features of sorbent material are of great importance to ensure extraction efficiency from one side and selectivity from the other side of the SPE procedure. This review presents an update on the application of polymeric materials in solid-phase extraction used in nonchromatographic methods for speciation analysis.

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