Spectral and thermal characterization of salophen type Schiff base and its implementation as solid contact electrode for quantitative monitoring of copper(II) ion

Demir, Serkan; Yilmaz, Hakan; Dilimulati, Maowulidan; Andaç, Müberra

doi:10.1016/j.saa.2015.05.093

Cited by 9 publications

(5 citation statements)

References 51 publications

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“…Also, in comparison with the ligand, the imine proton resonances shi to downeld and appear at 9.02 ppm and 8.97 ppm which conrm the coordination of nitrogen atoms of imine groups to the Ni(II) center (in the 1 H NMR spectrum of the ligand, the two noneequivalent imine proton resonances are observed at 8.95 ppm and 8.99 ppm). 27,28 Moreover, the aromatic protons are observed at 6.73-8.32 ppm and the protons of -CH 3 group appear at 2.14 ppm ( Fig. S3 †).…”

Section: Synthesis and Characterizationmentioning

confidence: 99%

Electrocatalytic water oxidation by a Ni(ii) salophen-type complex

et al. 2019

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Section: Synthesis and Characterizationmentioning

confidence: 99%

Electrocatalytic water oxidation by a Ni(ii) salophen-type complex

et al. 2019

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“…A Cu(II) selective ionophore based on a salophen templated schiff base, 2,3-bis(salicylaldimino)pyridine, was characterized by the group of Demir in solid state ion-selective electrodes . The reported selectivity coefficients were rather modest, and the small electrode slopes to interfering ions hinting at significant experimental bias in the data.…”

Section: Ionophoresmentioning

confidence: 99%

Electroanalysis with Membrane Electrodes and Liquid–Liquid Interfaces

Bakker

2015

Anal. Chem.

100

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This Review describes, with 200 references, progress with ion-selective electrodes, membrane electrodes, and ion transfer voltammetry in the period between January 2013 and September 2015. The selection of papers was done at the author’s discretion and should therefore be understood as an opinion piece and a current snapshot of the activity in the field. Contributions were sourced from modern search engines, primarily SciFinder, searching for relevant keywords and known author names. Some journal tables of contents were also screened manually. Please accept my apology if a reader feels that his or her important contribution has been left out. Perhaps I simply did not see it

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“…Nitrite-selective PVC-based membrane solid contact electrodes were prepared in the same manner as described in our previous work. 42 The electrodes were prepared in two steps. In the first step, a conductive solid contact was prepared by using an appropriate mass ratio of graphite, epoxy and hardener.…”

Section: Preparation Of Electrodesmentioning

confidence: 99%

A new Co(III) complex of Schiff base derivative for electrochemical recognition of nitrite anion

et al. 2017

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The synthesis and characterization of a new Co(III) complex of a salphen-type Schiff base ligand, (E)-2-{[(2-aminopyridin-3-yl)imino]methyl}-4,6-di-tert-butylphenol (HL), are reported. The characterization has been carried out using X-ray single crystallographic, thermogravimetric, and spectroscopic techniques. The complex has been combined with polyvinyl chloride (PVC) membrane of various compositions and tested as an electrochemical electrode towards recognition of several anions. The electrode exhibits exceptional electrochemical recognition for the nitrite (NO − 2) anion in aqueous media. The electrode exhibited a linear response to NO − 2 with a detection limit of 5.76 μM and displayed a linear Nernstian slope over the nitrite concentration range of 1.0 × 10 −5-1.0 × 10 −1 M in the pH range of 3-7 and a fast response time of less than 10 seconds. Theoretical calculations showed that the sensing could be via anion exchange in the Co(III) complex.

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Spectral and thermal characterization of salophen type Schiff base and its implementation as solid contact electrode for quantitative monitoring of copper(II) ion

Cited by 9 publications

References 51 publications

Electrocatalytic water oxidation by a Ni(ii) salophen-type complex

Electrocatalytic water oxidation by a Ni(ii) salophen-type complex

Electroanalysis with Membrane Electrodes and Liquid–Liquid Interfaces

A new Co(III) complex of Schiff base derivative for electrochemical recognition of nitrite anion

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