Spectral hole burning in free perylene and in small clusters with methane and alkyl halides

Wittmeyer, Stacey A.; Topp, Michael R.

doi:10.1016/0009-2614(89)80047-8

Cited by 57 publications

(22 citation statements)

References 33 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In such an experimental setup the pump laser reduces the population of a subset of states by a substantial amount and then the result is probed by a second laser that is scanned through the spectral range of interest. Spectral hole burning has been applied in cluster research to unravel line shapes [6,7] or to confidently distinghuish vibronic bands from overlapping resonances due to other cluster sizes without using a mass spectrometer [8,9]. Double resonance has been successfully employed to measure the number of absorbed photons in an IR predissociation experiment with bolometer detection [10] or to characterize a precursor complex in an intra-cluster reaction [i 1].…”

Section: Introductionmentioning

confidence: 99%

IR double resonance experiments with size selected clusters for identification of isomers

Buck¹,

Hobein²

1993

Z Phys D - Atoms, Molecules and Clusters

View full text Add to dashboard Cite

Abstract. Infrared photodissociation spectra of (CH3OH)n clusters (n = 2, 3 and 6) and the mixed dimer C2H 4. CH3COCH 3 are presented. The clusters are generated in a supersonic jet expansion and size selected by scattering from a helium atomic beam combined with mass spectrometric detection. Continuous CO2-1asers are used to vibrationally excite the molecules in the cluster leading to rapid dissociation of the complex. Various dissociation peaks that are found in single-laser dissociation spectra can be assigned unambigously in a pump-probe experiment with two lasers to either different isomers (acetone-ethene dimer) or splitted lines of one isomer (methanol hexamer). For size distributions, the method is able to select contributions of single masses which is demonstrated for mixtures of methanol dimers and trimers.

show abstract

Section: Introductionmentioning

confidence: 99%

IR double resonance experiments with size selected clusters for identification of isomers

Buck¹,

Hobein²

1993

Z Phys D - Atoms, Molecules and Clusters

View full text Add to dashboard Cite

show abstract

“…The hole on the probe signal occurs due to depletion in population when the pump frequency matches with any transition frequency of the probed species. 13 The highest purity 1-methoxynaphthalene was procured from Aldrich and was used as received.…”

Section: Methodsmentioning

confidence: 99%

Jet spectroscopy of van der Waals dimers of 1-methoxynaphthalene: A laser induced fluorescence study

Das

Mahato

Chakraborty

2001

The Journal of Chemical Physics

View full text Add to dashboard Cite

Articles you may be interested inVibrations of porphycene in the S0 and S1 electronic states: Single vibronic level dispersed fluorescence study in a supersonic jet Structure and electronic spectroscopy of naphthalene-acenaphthene van der Waals dimer: Hole-burning, dispersed fluorescence, and quantum chemistry calculations Excited state dynamics following S 1 ←S 0 transition of jet-cooled van der Waals complexes of 1-methoxynaphthalene has been investigated by measuring the laser-induced fluorescence excitation, dispersed fluorescence and two-color hole-burning spectra. The results give evidence of formation of two isomeric dimers, which show only sharp absorption and emit excimer fluorescence for excitations to the origin region of the S 1 state. Excimer formation in one of the dimers occurs from the zero-point level of the locally excited state. The other dimer shows vibrational barrier and the yield of the excimer emission increases as the successive higher quanta of a low-frequency intermolecular mode are excited. The barrier in the second case has been attributed to the reorganization of the dimer geometry from the locally excited state to the excimer state. The characteristic enhancement of the yield of excimer emission with increase in excitation energy indicates the involvement of a tunneling mechanism for crossing the reorganization barrier.

show abstract

“…Hence this method can be used to distinguish between different cluster sizes, conformers, and hot vibrational states. [1][2][3] SHB-R2PI may be the most powerful tool up to now for a first insight into the cluster puzzle. For investigation of the electronic ground state S 0 of a cluster and its vibrational states, several double resonance techniques have been developed.…”

Section: Introductionmentioning

confidence: 99%

Intermolecular vibrations of the phenol dimer revealed by spectral hole burning and dispersed fluorescence spectroscopy

Schmitt¹,

Henrichs²,

Müller³

et al. 1995

The Journal of Chemical Physics

View full text Add to dashboard Cite

show abstract

Spectral hole burning in free perylene and in small clusters with methane and alkyl halides

Cited by 57 publications

References 33 publications

IR double resonance experiments with size selected clusters for identification of isomers

IR double resonance experiments with size selected clusters for identification of isomers

Jet spectroscopy of van der Waals dimers of 1-methoxynaphthalene: A laser induced fluorescence study

Intermolecular vibrations of the phenol dimer revealed by spectral hole burning and dispersed fluorescence spectroscopy

Contact Info

Product

Resources

About