2017
DOI: 10.1088/1742-6596/867/1/012039
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Spectral photosensitization of optical anisotropy in poly(vinyl cinnamate) solid films

Abstract: Abstract.We observed possibilities and properties of sensitized photo induced optical anisotropy formation in amorphous poly (vynyl-cinnamate) films (PVCi) and its derivant poly (vynyl-4-methoxy-cinnamate) (PVMCi) under polarized light, including the one which is not absorbed by the supermolecules of the polymeric material. The effect of the induced optical anisotropy involves transferring the energy of electronic excitation from the donor molecules (Michler's ketone or 2-benzoyl-methylene-3, methyl-β-naphthos… Show more

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Cited by 14 publications
(1 citation statement)
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“…We believe that the effect can take place due to the photoinduced ordering of MR molecules under the action of non-polarized light in such a way that their transition dipole moments become parallel to the direction of light propagation. Similar effect of the photo-induced molecular ordering was found in some photochemically stable azo dyes in polymer matrix [35], amorphous film of azo dyes formed by vacuum evaporation [36] or spincoating [37] and Langmuir-Blodgett films [38]. Liquid Crystals and their Application.…”
Section: Pia Determined From Dichroic Spectramentioning
confidence: 60%
“…We believe that the effect can take place due to the photoinduced ordering of MR molecules under the action of non-polarized light in such a way that their transition dipole moments become parallel to the direction of light propagation. Similar effect of the photo-induced molecular ordering was found in some photochemically stable azo dyes in polymer matrix [35], amorphous film of azo dyes formed by vacuum evaporation [36] or spincoating [37] and Langmuir-Blodgett films [38]. Liquid Crystals and their Application.…”
Section: Pia Determined From Dichroic Spectramentioning
confidence: 60%