The composite scintillators from inorganic scintillators and organic phosphors provide unique combination of high light yield and nanosecond temporal resolution. Preparation of microfibers of these composites by means of centrifugation resulted in forming of axial nanosplitting and transverse micromodulation of their structure and optical properties, These modulations result in essential improvement of scintillation parameters of the composite providing the development of relatively simple and cheap X-Ray microscope. Ball rolling of inorganic solids provides superfast introduction of organic and inorganic components into subsurface layers for the special modifications of their properties. The superfast introduction is explained by propagation of nanocracks involving necessary dopants into the solid.