“…12 for (ZrO 2 ) 92 (Y 2 O 3 ) 8-x (Nd 2 O 3 ) x single crystals with different Nd 2 O 3 contents. These all show the three emission bands corresponding to the Nd 3+ 4 F 3/2 → 4 I 9/2 (894/957 nm), 4 F 3/2 → 4 I 11/2 (1064/1128 nm), and 4 F 3/2 → 4 I 13/2 (1332 nm) transitions that are characteristic of Nd 3+ doped materials, [43][44][45] but the narrow linewidths in these single crystal samples allow each of the first two bands to be resolved into two components, which are related to distortions in the local environment for Nd 3+ in (ZrO 2 ) 92 (Y 2 O 3 ) 8−x (Nd 2 O 3 ) x single crystals. Of these, the main emission maximum occurs at 1064 nm, and can be used for lasers with an emission wavelength of around 1.06 μm.…”
Section: Near-infrared Luminescence and Mechanismmentioning
Transparent single crystals of (ZrO2)92(Y2O3)8-x(Nd2O3)x ( x=0.30, 0.50, 0.75, 1.00, 1.25, 1.50) were prepared by the optical floating zone method, and shown by XRD to have a cubic phase structure....
“…12 for (ZrO 2 ) 92 (Y 2 O 3 ) 8-x (Nd 2 O 3 ) x single crystals with different Nd 2 O 3 contents. These all show the three emission bands corresponding to the Nd 3+ 4 F 3/2 → 4 I 9/2 (894/957 nm), 4 F 3/2 → 4 I 11/2 (1064/1128 nm), and 4 F 3/2 → 4 I 13/2 (1332 nm) transitions that are characteristic of Nd 3+ doped materials, [43][44][45] but the narrow linewidths in these single crystal samples allow each of the first two bands to be resolved into two components, which are related to distortions in the local environment for Nd 3+ in (ZrO 2 ) 92 (Y 2 O 3 ) 8−x (Nd 2 O 3 ) x single crystals. Of these, the main emission maximum occurs at 1064 nm, and can be used for lasers with an emission wavelength of around 1.06 μm.…”
Section: Near-infrared Luminescence and Mechanismmentioning
Transparent single crystals of (ZrO2)92(Y2O3)8-x(Nd2O3)x ( x=0.30, 0.50, 0.75, 1.00, 1.25, 1.50) were prepared by the optical floating zone method, and shown by XRD to have a cubic phase structure....
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