Spectroscopic investigation of proton-conducting, cross-linked linear poly(ethylenimine) hydrochloride membranes

Giffin, Guinevere A.; Castillo, Frank Yepez; Frech, Roger; Glatzhofer, Daniel T.; Burba, Christopher M.

doi:10.1016/j.polymer.2008.10.051

Cited by 11 publications

(5 citation statements)

References 29 publications

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“…Many researchers are interested in hydrocarbon polymers with an aliphatic main chain for PEMs. However, this kind of PEM is mainly used for low-temperature PEMFC or DMFC due to the inferior oxidative stability of these aliphatic main-chain hydrocarbon polymers. − The frequently used aliphatic main-chain hydrocarbon polymers include varieties of styrene-based block copolymers, CS, poly(vinyl alcohol) (PVA), and so on. To enhance mechanical strength, methanol barrier, or proton conductivity, these polymers often require doping with inorganic proton-conducting moieties, blending with polymer pairs, or forming into IPNs.…”

Section: Nonfluorinated Acid Ionomer Membranesmentioning

confidence: 99%

Recent Development of Polymer Electrolyte Membranes for Fuel Cells

2012

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Membranes with Proton-Conducting Polymer Components 2793 4. Nonfluorinated Acid Ionomer Membranes 2793 4.1. Poly(arylene ether)-Based Membranes 2793 4.1.1. Modification of SPEEK Membrane 2793 4.1.2. Poly(arylene ether)s with Cross-Linkable Groups 2794 4.1.3. Poly(arylene ether)s with Pendant Sulfonated Groups or Side-Chains 2799 4.1.4. Poly(arylene ether)s with Backbones Containing Heteroatoms Such as F, N, S, and P 2800 4.1.5. Multiblock Copoly(arylene ether)s Synthesized by the Coupling Reaction of Hydrophilic and Hydrophobic Macromonomers 2803 4.2. Polyimide-Based Membranes 2804 4.2.1. SPIs Based on NTDA 2804 4.2.2. SPIs based on BNTDA 2806 4.2.3. SPIs Based on Other Dianhydrides 2807 4.3. Hydrocarbon Polymer with Aliphatic Main-Chain-Based Membranes 2807 4.4. Glass Membranes 2809 5. Polybenzimidazole/H 3 PO 4 Membranes 2809 5.1. Modifications to mPBI 2810 5.1.1. Optimizations of Preparation and Operation of Acid-Doped mPBI System 2810 5.1.2. Modified mPBI/H 3

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Section: Nonfluorinated Acid Ionomer Membranesmentioning

confidence: 99%

Recent Development of Polymer Electrolyte Membranes for Fuel Cells

2012

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“…123 But the most common use of ex situ Raman spectroscopy remains to check chemical composition and structure of new composite membranes. [124][125][126][127][128][129][130][131] Only recently, further progress of the Raman microscopy technique (confocal mode) has allowed us to measure in situ concentration profiles of molecular species diffusing across the polymer film. 114,[132][133][134][135][136][137][138][139][140][141] Fig.…”

Section: Confocal Micro-raman Spectroscopymentioning

confidence: 99%

3 In situ and operando determination of the water content distribution in proton conducting membranes for fuel cells: a critical review

Deabate¹,

Gebel²,

Huguet³

et al. 2012

Energy Environ. Sci.

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“…Several different types of membranes are currently being investigated, including poly(perfluorosulfonic acids) [3,4], sulfonated poly(arylenes) [5][6][7][8][9][10], and acid-doped polymer complexes [11][12][13][14][15][16]. A cross-linked linear poly(ethylenimine) hydrochloride/phosphoric acid system, using 1,1,3,3-tetramethoxypropane as the cross-linker, has been presented as a potential membrane alternative that has good conductivity, mechanical integrity and thermal stability up to 150ºC [17,18].…”

Section: Introductionmentioning

confidence: 99%

New Polymer Assembles with Potential Use as Solid Electrolytes Type Membranes

Maior

Albu

Gabor

2015

AMM

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Solid polymer electrolyte (SPE) membranes with varying composition ratios were prepared from poly(vinyl alcohol) (PVA), poly(acrylic acid) (PAA) and poly(metacrylic acid) (PMMA). The acrylic acid monomer with cross-linker was first blended with PVA polymer. A free radical polymerization was then carried out to form an alkaline polymer electrolyte. The solution casting method was used to form the solid polymer membranes. The solid polymer membranes were characterized by FT-IR spectroscopy, SEM morphology analysis and electrochemical impedance spectroscopy. The results showed that at room temperature the highest ionic conductivity for the PVA/PAA/KOH solid polymer membrane electrolyte system was 4.54·10-8 Ω-1 cm-1. The PVA/PAA polymer membrane had good mechanical strength and ductility and would be a suitable polymer membrane electrolyte for the alkaline batteries and other electrochemical systems.

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Spectroscopic investigation of proton-conducting, cross-linked linear poly(ethylenimine) hydrochloride membranes

Cited by 11 publications

References 29 publications

Recent Development of Polymer Electrolyte Membranes for Fuel Cells

Recent Development of Polymer Electrolyte Membranes for Fuel Cells

3 In situ and operando determination of the water content distribution in proton conducting membranes for fuel cells: a critical review

New Polymer Assembles with Potential Use as Solid Electrolytes Type Membranes

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