Spectroscopic parameters of Ce3+ ion doped Na2CaMg(PO4)2 phosphor

Extraction of crystal-field parameters for lanthanide ions from quantum-chemical calculations

“…This is an important application, as there is considerable interest in phosphors that make use of the 5d → 4f transitions. [44,45] Since crystal-field parameters are transferable to other ions in the lanthanide series, another application of our approach is to derive parameters from calculations from Ce 3+ , for which ab initio calculations are manageable than for a system with many 4f electrons, and then scale those parameters for crystal-field calculations for other ions.…”

Conversion of broadband UV-visible light to near infrared emission by Ca14Zn6Al10O35: Mn4+, Nd3+/Yb3+

“…The commonly accepted view is that the formative Ca vacancies can compensate charge imbalance. [26][27][28] When Nd 3+ /Yb 3+ ions are co-doped into Ca 14 Zn 6 Al 10 O 35 matrix, the Ca vacancies might form and they could keep the electroneutrality of the compound. The diffuse reection spectra of Ca 14 Zn 6 Al 10 O 35 doped with Mn 4+ , Nd 3+ and Yb 3+ ions are shown in Fig.…”

Correlation between structure and photoluminescence of the europium doped glaserite-type phosphate Na2SrMg(PO4)2

“…Na 2 CaMg(PO 4 ) 2 exhibits a reversible phase transition at (1078 AE 5)K from the monoclinic space group P2 1 /c to the trigonal one P3 m1 [16]. The luminescence properties of its Eu 2þ and Ce 3þ doped phases were discussed in detail [4,21].…”