Spectroscopic properties and concentration effects on luminescence behavior of Nd3+ doped Zinc–Boro–Bismuthate glasses

Sontakke, Atul D.; Annapurna, K.

doi:10.1016/j.matchemphys.2012.11.002

Cited by 45 publications

(16 citation statements)

References 22 publications

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“…Here, most of the expected transitions fluorescence signals and radiative lifetimes were recorded, so that the cross-section could be calculated for 2S2G glass. Emission cross section are quite higher compare to Ga-Ge-S-CsCl system which is about 0.5x10 −20 cm 2 for the 4 F 3/2 → 4 I 13/2 transition [68], and a bit lower compare to Zn-Bi borate system (4x10 −20 cm 2 ) for the 4 F 3/2 → 4 I 11/2 transition [69]. (Fig.…”

Section: Spectroscopy Of Nd 3+ In Ga 5 Ge 20 Sb 10 S 65 and Ga 5 Ge 2mentioning

confidence: 86%

Nd³⁺:Ga-Ge-Sb-S glasses and fibers for luminescence in mid-IR: synthesis, structural characterization and rare earth spectroscopy

Chahal¹,

Starecki²,

Doualan³

et al. 2018

Opt. Mater. Express

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With high refractive indices, appropriate solubility of rare earth, low phonon energy and transparency from the visible to 10 µm, a GaGe -Sb-S system allows emission from Nd 3+ ions in the near-and mid-IR spectral ranges. The glass transition temperature, density, expansion coefficient, and near and mid-IR refractive indexes were measured on bulk samples. Their glass network structures were analyzed by Raman scattering spectrometry, NMR of 71 Ga and extended X-ray absorption fine structure (EXAFS, K-edge of Ga, Ge, Sb, S and Nd). The absorption and emission spectra of neodymium doped sulfide glasses were recorded from the visible to the mid-IR. Excited state lifetimes were measured for several transitions. The lifetimes decrease with the concentration of Nd 3+ , especially for the 4 I 13/2 and 4 I 11/2 levels. The spectroscopic parameters were determined by the Judd-Ofelt method, allowing the calculation of cross-section emissions and the evaluation of quantum yields. Optical attenuation and emission measurements of fiber were also performed with a broad 4.7-5.7 µm emission band in the mid-IR.

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Section: Spectroscopy Of Nd 3+ In Ga 5 Ge 20 Sb 10 S 65 and Ga 5 Ge 2mentioning

confidence: 86%

Nd³⁺:Ga-Ge-Sb-S glasses and fibers for luminescence in mid-IR: synthesis, structural characterization and rare earth spectroscopy

Chahal¹,

Starecki²,

Doualan³

et al. 2018

Opt. Mater. Express

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“…For the intensity of the emission spectra of glass‐ceramics, it attains a maximum at 2.0 mol.% Nd 2 O 3 concentrations and then decreases with further increase in dopant concentration. This is because as the Nd 2 O 3 concentration continues to increase in the glass‐ceramics, the distance between the Nd 3+ ions decreases and the interaction between Nd 3+ ions enhances, resulting in an enhancement of the cross‐relaxation process between Nd 3+ ions, which inevitably depopulates the Nd 3+ ions located at the 4 F 3/2 level . Therefore, when the Nd 2 O 3 concentration exceeds a certain amount, the intensity of the emission spectrum of glass‐ceramics decreases.…”

Section: Resultsmentioning

confidence: 99%

A novel Nd³⁺‐doped MgO‐Al₂O₃‐SiO₂‐based transparent glass‐ceramics: Toward excellent fluorescence properties

Han

Lin

et al. 2019

J Am Ceram Soc

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Generally, glass-ceramics have superior properties compared to their parent glasses. Here, we prepared a novel Nd 3+ -doped MgO-Al 2 O 3 -SiO 2 -based transparent glass-ceramics with excellent fluorescence properties. The effects of Nd 2 O 3 content on the structure and properties of glass-ceramics were studied, aiming to provide a key guidance for preparing this transparent glass-ceramics. The results revealed that the glass stability increased originally and then decreased with increasing Nd 2 O 3 content, so did the variation of wavenumbers in infrared spectra. And these glass-ceramics are mainly composed of cordierite with residual glassy phase. The three phenomenological intensity parameters (Ω 2,4,6 ) and radiative properties were estimated by Judd-Ofelt theory, and the values of Ω 2 first decreased and then increased with increasing Nd 2 O 3 content. Three main emission peaks ascribed to the transitions from 4 F 3/2 to 4 I 9/2 , 4 I 11/2 , 4 I 13/2 at 898, 1057, 1330 nm were observed, respectively. The branching ratios for 4 F 3/2 → 4 I 11/2 transition increased as the Nd 2 O 3 content raised, and the fluorescence lifetimes of the 4 F 3/2 level were found to increase first and then decrease with Nd 2 O 3 content (from 181 to 726 μs). The excellent fluorescence properties indicate that this novel glass-ceramics can be used as a potential solid-state optical functional material for 1.06 μm laser emission. K E Y W O R D SJudd-Ofelt theory, MgO-Al 2 O 3 -SiO 2 , Nd 3+ -doped, solid-state optical functional materials, transparent glass-ceramics

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“…The h value for 1.06 mm emissions has been calculated to be 90% in 0.5 mol% Nd 2 O 3 doped bismuth silicate glass, which is larger than those of zinceboroebismuthate glasses (50.5e80.4%) [32] and bismuth zinc borate glass (43%) [8]. Results indicate that the prepared samples have potential applications in 1.06 mm laser.…”

Section: Emission Spectra and Fluorescence Lifetimesmentioning

confidence: 89%

Concentration dependence of spectroscopic properties and energy transfer analysis in Nd 3+ doped bismuth silicate glasses

Tian

Chen

Shuibao

2015

Solid State Sciences

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Spectroscopic properties and concentration effects on luminescence behavior of Nd3+ doped Zinc–Boro–Bismuthate glasses

Cited by 45 publications

References 22 publications

Nd³⁺:Ga-Ge-Sb-S glasses and fibers for luminescence in mid-IR: synthesis, structural characterization and rare earth spectroscopy

Nd³⁺:Ga-Ge-Sb-S glasses and fibers for luminescence in mid-IR: synthesis, structural characterization and rare earth spectroscopy

A novel Nd³⁺‐doped MgO‐Al₂O₃‐SiO₂‐based transparent glass‐ceramics: Toward excellent fluorescence properties

Concentration dependence of spectroscopic properties and energy transfer analysis in Nd 3+ doped bismuth silicate glasses

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Spectroscopic properties and concentration effects on luminescence behavior of Nd3+ doped Zinc–Boro–Bismuthate glasses

Cited by 45 publications

References 22 publications

Nd3+:Ga-Ge-Sb-S glasses and fibers for luminescence in mid-IR: synthesis, structural characterization and rare earth spectroscopy

Nd3+:Ga-Ge-Sb-S glasses and fibers for luminescence in mid-IR: synthesis, structural characterization and rare earth spectroscopy

A novel Nd3+‐doped MgO‐Al2O3‐SiO2‐based transparent glass‐ceramics: Toward excellent fluorescence properties

Concentration dependence of spectroscopic properties and energy transfer analysis in Nd 3+ doped bismuth silicate glasses

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Nd³⁺:Ga-Ge-Sb-S glasses and fibers for luminescence in mid-IR: synthesis, structural characterization and rare earth spectroscopy

Nd³⁺:Ga-Ge-Sb-S glasses and fibers for luminescence in mid-IR: synthesis, structural characterization and rare earth spectroscopy

A novel Nd³⁺‐doped MgO‐Al₂O₃‐SiO₂‐based transparent glass‐ceramics: Toward excellent fluorescence properties