2001
DOI: 10.1006/jcis.2001.7490
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Spectroscopic Study of Cm(III) Sorption onto γ-Alumina

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Cited by 73 publications
(69 citation statements)
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“…4A and B, the I 593 /I 617 peak ratio clearly depends on the pH of the suspension and decreases with increasing pH. This behaviour is in good agreement with the results of many studies (Stumpf et al, 2001;Stumpf et al, 2002a,b;Kowal-Fouchard et al, 2004;Rabung et al, 2005). We attribute this effect to a pH-related change in the atomic environment of the sorbed Eu(III), as suggested by the fluorescence time measurements.…”
Section: Trlfs Spectrum Of Sorbed Eu(iii)supporting
confidence: 89%
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“…4A and B, the I 593 /I 617 peak ratio clearly depends on the pH of the suspension and decreases with increasing pH. This behaviour is in good agreement with the results of many studies (Stumpf et al, 2001;Stumpf et al, 2002a,b;Kowal-Fouchard et al, 2004;Rabung et al, 2005). We attribute this effect to a pH-related change in the atomic environment of the sorbed Eu(III), as suggested by the fluorescence time measurements.…”
Section: Trlfs Spectrum Of Sorbed Eu(iii)supporting
confidence: 89%
“…Previous studies on lanthanide/clay systems using similar experimental protocols (Stumpf et al, 2001(Stumpf et al, , 2002aCoppin et al, 2002;Kowal-Fouchard et al, 2004;Rabung et al, 2005) have shown that Ln(III)-bearing phases do not precipitate during sorption experiments conducted at 25°C. This was suggested by the consistence of the sorption data and further supported by TRLFS data (Stumpf et al, 2002a,b;Kowal-Fouchard et al, 2004).…”
Section: Trlfs Spectrum Of Sorbed Eu(iii)mentioning
confidence: 94%
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“…Although the incorporation of radionuclides into the bulk structure represents another very important mechanism for their retardation, very little is known about these processes. Only a very few systematic studies for investigating the incorporation mechanisms in the trace concentration range have been performed (7)(8)(9). As a consequence these processes are in general neglected in the performance assessment of a nuclear waste repository.…”
Section: Introductionmentioning
confidence: 99%