In this paper, we present an experimental study of the hexagonal compound Na 0.70 MnO 2 . Zero-field-cooled and field-cooled susceptibilities display divergences at low temperatures, and the magnetic measurements of frequency dependence of ac susceptibility, hysteresis effect, and long-time relaxation are performed, indicating that Na 0.70 MnO 2 undergoes a spin-glass transition at T f = 39 K. The spin-glass order parameter q͑T͒ determined from the dc spin susceptibility exhibits the relation q͑T͒ ϰ ͑1−T / T f ͒, in agreement with the prediction of conventional spin-glass theory. Spin dynamics in the spin-glass state is carefully examined, and the time decay of the thermoremanent magnetization can be well scaled with a reduced effective waiting time / t w . The magnetic entropy extracted from the specific heat implies that the spin degrees of freedom of Mn 3+ /Mn 4+ ions are completely frozen at low temperatures, and the origin of this spin-glass behavior is attributed to the mixture of Mn 3+ /Mn 4+ ions and geometrical frustrations on the triangular lattices. Comparisons with the magnetic properties of Na 0.70 CoO 2 are also made.