An ion beam sputtering technique has been developed which made possible the production of homo-epitaxial Si layers by sputtering for the first time. The A+ ion beam source was considerably modified from the initial design of Hill and Nelson (1965) to give the purity needed for the production of semiconductor layers without mass analysis of the ion beam. Typically, a 12keV 4mA beam of A+ ions struck a Si target at 60° incidence and ejected sputtered atoms were deposited at a rate of 200 A/min on a heated Si(111) substrate placed just above the target. Epitaxial layers were grown at temperatures above about 700°C and the structural quality of these layers was evaluated by transmission electron microscopy. Layers grown at temperatures in excess of 900°C contained only dislocation defects normally to a density of about 8x109 cm-2, whereas epitaxial layers grown at lower temperatures also exhibited stacking faults and microtwinning. The existence of defects in epitaxial layers has been correlated with the severity of bombardment of the substrate during deposition by secondary ions from the target. In all cases, the bombardment conditions were severe enough to continually transform a thin 100 A thick surface region of the newly-deposited sputtered layer to a disordered state. The subsequent reordering characteristics of this disordered surface controlled not only the prominence of individual defects in any epitaxial layer but also whether a layer was single crystal. Electrical properties of epitaxial layers were also strongly dependent on bombardment conditions allowing only high resistivity N-type layers to be grown independent of target conductivity-type and resistivity.The ion beam sputtering properties of Si and GaAs have also been investigated. The similarity in results for single crystal targets to those for polycrystalline targets was again attributed to ion-bombardment-induced surface disorder. Stoichiometric layers of GaAs could only be obtained from polycrystaline targets.