“…At present, plasma based Physical Vapour Deposition (PVD) technologies are currently used for the preparation and industrial production of thin films and coatings . The relationships between the deposition conditions used for the formation of thin films and coatings, as well as their elemental and phase composition, structure, microstructure and final physical and functional properties are intensively investigated . However, much less attention is paid to basic micro‐parameters of the discharge plasma, such as the electron density, N e , electron temperature, T e , degree of gas ionization, amount of atoms, creation of radicals and energy distribution functions of these species, i.e.…”