Square wave polarography and some related techniques

Barker, G.C.

doi:10.1016/s0003-2670(00)87111-1

Cited by 281 publications

(77 citation statements)

References 5 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Nowadays it is considered as one of the most advanced voltammetric techniques, which unifies the advantages of pulse techniques (enhanced sensitivity), cyclic voltammetry (insight into the electrode mechanism) and impedance techniques (kinetic information of very fast electrode processes). In a historical context, it originates from the Kalousek commutator [7] and Barkers square-wave polarography [8][9][10]. The modern SWV, incorporated in digital electrochemical instruments [1,11], utilizes a combination of a staircase potential modulation and periodic square-shaped potential function, applied at a stationary electrode.…”

Section: Introductionmentioning

confidence: 99%

Square‐Wave Voltammetry: A Review on the Recent Progress

et al. 2013

View full text Add to dashboard Cite

A review on the recent progress of square-wave voltammetry is presented, covering the period of the last five years. The review addresses the new theoretical development of the technique as well as its application for mechanistic purposes, electrode kinetic measurements, biochemical and analytical applications. Besides, a few novel methodological modifications are proposed that might expand the scope and application of the technique.

show abstract

Section: Introductionmentioning

confidence: 99%

Square‐Wave Voltammetry: A Review on the Recent Progress

et al. 2013

View full text Add to dashboard Cite

show abstract

“…Its use, however, has been restricted primarily to the gathering of qualitative information. Quantitative determinations are better made by other electroanalytical techniques such as differential-pulse (5,6) and square-wave voltammetry (5,7,8). By comparison these latter techniques offer increased sensitivity over CV due to their ability to effectively separate charging current, which contributes largely to the background, from the faradaic current and interpretation of the peak readout is much simpler.…”

Section: Introductionmentioning

confidence: 99%

Pulse cyclic voltammetry. I. Static solutions

Eccles¹,

Purdy²

1987

Can. J. Chem.

View full text Add to dashboard Cite

This paper is dedicated to Professor Douglas E. Ryan on the occasio~l of his 65th birthdayGORDON N. ECCLES and WILLIAM C. PURDY. Can. J. Chem. 65, 105 1 (1987).By using pulse cyclic voltammetry rather than cyclic voltammetry at a relatively high scan rate, an increase in sensitivity and a lowering of the detection limit by more than a factor of two are demonstrated for the ferricyanide-ferrocyanide couple at a carbon electrode. The test for reversibility based on peak shape or symmetry comparison is enhanced significantly with pulse cyclic voltammetry. Another reversibility test, by observing peak variations as a function of scan rate, was applied to pulse cyclic voltammetry and was found to be as diagnostically informative as the cyclic voltammetry test. These tests are illustrated by a study of the hydroquinone-quinone couple. Dans le cas du couple ferricyanure/ferrocyanure ii une electrode de carbone, on dCmontre que l'utilisation de la voltamCtrie cyclique pulsCe plut6t que la voltamCtrie cyclique B des taux de balayage relativement ClevCs augmente la sensibilitC et diminue la limite de detection par un facteur qui est plus grand que deux. Avec la voltamCtrie cyclique, on augmente considCrablement le test pour la rCversibilitC qui est bask sur la forme du maximum ou sur une comparaison de la symCtrie. On a aussi appliquC un autre test de rCversibilitC, bask sur les variations des maxima observCs en fonction du taux de balayage, B la voltamktrie pulsCe et on a trouvC que ce test permet un aussi bon diagnostique que le test de la voltamCtrie cyclique. On illustre ces tests par une Ctude du coupe hydroquinone/quinone.[Traduit par la revue]

show abstract

“…2C the inductor is also represented by an equivalent parallel circuit. The resonant condition, in general, is given by (12) Accordingly, one is lead to the following relationship, (13) and (14) These parallel components are equivalent to the series components given in Fig. 2B, so that is renewed every 2 or 3 sec, so that the contamination is much smaller than in the case of the hanging by the DME were much higher, as shown in Tables 1 and 2.…”

mentioning

confidence: 99%

Faradaic Impedance of Fast Electrode Processes as Measured by an Impedance Bridge Using an Inductor

Tanaka¹,

Imai²

1968

Bulletin of the Chemical Society of Japan

View full text Add to dashboard Cite

An impedance bridge using an inductor in parallel with the cell is proposed for accurate measurement of kinetic parameters of fast electrode processes. The theory and method of analysis are given in detail. Its applicability was proved up to at least 50 kc, and possibly at higher frequencies. The kinetic parameters obtained by this method for the electrode reaction Cd2++2e=Cd(Hg) in m Na2SO4 at the D. M. E. were α=0.17, and k°=0.064 cm/sec (25°C).

show abstract

Square wave polarography and some related techniques

Cited by 281 publications

References 5 publications

Square‐Wave Voltammetry: A Review on the Recent Progress

Square‐Wave Voltammetry: A Review on the Recent Progress

Pulse cyclic voltammetry. I. Static solutions

Faradaic Impedance of Fast Electrode Processes as Measured by an Impedance Bridge Using an Inductor

Contact Info

Product

Resources

About