Natural convection with an electric field in the classic differentially heated square cavity is numerically studied. The electric conduction model for the generation of free space charges, which applies to weak and moderate electric field with weakly conducting liquids, is specially considered. The whole set of governing equations is implemented in the open-source finite-volume framework of OpenFOAM. The flow morphology and temperature distribution for pure natural convection and pure electric case are first presented. Then, the heat and flow characteristics for electro-thermo convection are carefully investigated. It is found that the application of electric field shows a suppression effect on the flow motion at all Rayleigh numbers (Ra) considered, which is consistent with the recent experimental finding. The weaker flow strength and thicker thermal boundary layer are observed for a larger conduction number (C0). Correspondingly, the overall heat transfer is suppressed by the electric field, and the Nusselt number (Nu) decreases with increasing C0. The torques induced by electric force and buoyancy force are calculated to illustrate the mechanism of electric field affecting natural convection. Finally, the relative Nusselt number (Rnu) is defined to show the effect of reducing heat loss. It is found that there is a critical Ra corresponding to minimal Rnu, and for large Ra, the Rnu almost keeps constant with increasing Ra.