The aim of this work was to study the influence of some imidazoliumbased ionic liquids (ILs) on the dispersion stability, volumetric properties, and viscosity of some polyethylene glycol 200 (PEG200) nanofluids containing ZnO nanoparticles. The particle size distribution of the systems has been studied by UV−Vis and dynamic light scattering (DLS). The results show that the ILs increase the stability of nanofluids. However, when the length of the alkyl chain of the ILs increased, the stability of nanofluids exhibited a decline. Additionally, to understand the molecular interactions between ILs, ZnO, and PEG200, the density (ρ), speed of sound (u), and viscosity (η) were measured at 293.15 to 308.15 K. The increase and decrease in some thermodynamic properties can help us discuss the stability behavior of nanofluids. Moreover, some theoretical analyses were performed using some well-known models and the respective calculated values were compared with those derived from experimental data.