Temperature-dependent
short-range structural evolution of Au44Ga56 liquid eutectic alloy has been studied by
in situ extended X-ray absorption fine structure (EXAFS), in situ
high-energy X-ray diffraction (HEXRD) together with first-principles
molecular dynamics (FPMD) simulations. It is found that the short-range
structure of Au44Ga56 liquid strongly inherits
the local atomic packing of the AuGa compound. A short-range structural
change in Ga-centered clusters is revealed by in situ EXAFS data at
the Ga K-edge at about 970 K, while no such change in Au-centered
clusters appears at the Au LIII-edge. The in situ HEXRD
and FPMD simulations also confirm the existence of a liquid-to-liquid
crossover (LLC) in the Au44Ga56 liquid at a
temperature range of about 1000–1100 K, mainly lying in the
local structural change around Ga atoms. Indeed, the alloys quenched
from the liquid phases below 1000 K and above 1100 K exhibit differences
in structure and magnetic properties, which opens a possibility to
fabricate new materials with different structures and properties in
LLC-containing alloys.