2012
DOI: 10.1134/s0036023612090173
|View full text |Cite
|
Sign up to set email alerts
|

Stability of the Mo72Fe30 polyoxometalate buckyball in solution

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

0
16
0
2

Year Published

2016
2016
2022
2022

Publication Types

Select...
8

Relationship

0
8

Authors

Journals

citations
Cited by 26 publications
(18 citation statements)
references
References 8 publications
0
16
0
2
Order By: Relevance
“…The first data on the transport properties of POM Mo 72 Fe 30 and Mo 132 were obtained with regard to their pure aqueous solutions, in particular, in the case of capillary electrophoresis. The diffusion coefficient for Mo 132 and Mo 72 Fe 30 ions in water was 1.8•10 −7 cm 2 /s (at a concentration of 4•10 −4 mol/l) and 7.3•10 −7 cm 2 /s (10 −5 mol/l), respectively [342,354]. The magnitude of the electrical mobility of these ions was similar and amounted to 6.4•10 −8 m 2 /V•s.…”
Section: Transport Characteristics Of Polyoxometalates: Modeling and mentioning
confidence: 94%
See 1 more Smart Citation
“…The first data on the transport properties of POM Mo 72 Fe 30 and Mo 132 were obtained with regard to their pure aqueous solutions, in particular, in the case of capillary electrophoresis. The diffusion coefficient for Mo 132 and Mo 72 Fe 30 ions in water was 1.8•10 −7 cm 2 /s (at a concentration of 4•10 −4 mol/l) and 7.3•10 −7 cm 2 /s (10 −5 mol/l), respectively [342,354]. The magnitude of the electrical mobility of these ions was similar and amounted to 6.4•10 −8 m 2 /V•s.…”
Section: Transport Characteristics Of Polyoxometalates: Modeling and mentioning
confidence: 94%
“…The absence of toxic Mo(V) in its structure and its electron-transport properties [340] [341]. In dilute aqueous solutions or at an increase in the medium pH, the POM clusters decompose over time into simpler compounds [342,343]. Mo 72 Fe 30 decomposes into compounds that are relatively harmless to the body.…”
mentioning
confidence: 99%
“…There is no long-term and substantial accumulation of POMs and their components in the body (various organs and tissues), as they are excreted by metabolism. This occurs, inter alia, due to the POM degradation into simpler components [106,137]. The issues of POM toxicity are discussed in more detail below.…”
Section: Nanocluster Polyoxometalates (Poms)mentioning
confidence: 99%
“…Кристаллографический размер такого ПОМ составляет около 2.5 нм. Он растворим в воде и образует в растворах многозарядные ионы, которые транспортируются под действием электрического поля [30]. Для ПОМ характерна постепенная деструкция в разбавленных растворах [30,31], при этом образующиеся более простые соединения молибдена и железа в дальнейшем могут включаться в естественные для организма процессы метаболизма.…”
Section: Introductionunclassified
“…Он растворим в воде и образует в растворах многозарядные ионы, которые транспортируются под действием электрического поля [30]. Для ПОМ характерна постепенная деструкция в разбавленных растворах [30,31], при этом образующиеся более простые соединения молибдена и железа в дальнейшем могут включаться в естественные для организма процессы метаболизма. Согласно [32][33][34][35] при различных способах введения и сроках экспозиции железо-молибденовых ПОМ отсутствуют как кумуляции железа и молибдена в различных органах крыс, так и выраженное токсическое действие.…”
Section: Introductionunclassified