Stable isotope fractionation of chlorine during the precipitation of single chloride minerals

Luo, Cheng; Xiao, Yaonan; Wen, Hao; Ma, Hao; Ma, Yunqi; Zhang, Yanling; Zhang, Yuxu; He, Maoyong

doi:10.1016/j.apgeochem.2014.06.005

Cited by 37 publications

(34 citation statements)

References 33 publications

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“…One important conclusion in Eastoe et al (2007) is: potash facies salt is in general (but not in detail in all cases) of lower d 37 Cl than halite facies salt. This is consistent with our experiments in Luo et al (2012Luo et al ( , 2014) (using TIMS measurements). Results using the two techniques were in good agreement.…”

Section: Analytical Techniques Have No Influence On Determination Thesupporting

confidence: 93%

“…In Eggenkamp et al (1995), the fractionation factors for the precipitation of NaCl, KCl and MgCl 2 Á6H 2 O from their saturated solutions were 1.00026, 0.99991 and 0.99994 respectively, the last two factors were lower than one. However, d 37 Cl values in other studies did not support this study (Xiao et al, 1994;Sun et al, 1998;Tan et al, 2005Tan et al, , 2009Eastoe et al, 2007;Luo et al, 2012Luo et al, , 2014. Whether the fractionation factors between salts and brines were greater than one?…”

Section: Introductioncontrasting

confidence: 60%

“…There are some conflicting findings about the fractionation between salts and the brine at present (Xiao et al, 1994(Xiao et al, , 2000Eggenkamp et al, 1995;Sun et al, 1998;Eastoe et al, 1999Eastoe et al, , 2007Tan et al, 2005Tan et al, , 2009Luo et al, 2012Luo et al, , 2014. In Eggenkamp et al (1995), the fractionation factors for the precipitation of NaCl, KCl and MgCl 2 Á6H 2 O from their saturated solutions were 1.00026, 0.99991 and 0.99994 respectively, the last two factors were lower than one.…”

Section: Introductionmentioning

confidence: 79%

“…We think it has to do with the method which we conducted the evaporation experiments. In Eggenkamp et al (1995), fractionation factors for a salt-solution were determined at a single point in the evolution of the evaporating system, not over the full extent of evaporation, but the method of experiments in our studies is progressive evaporation Luo et al (2012Luo et al ( , 2014.…”

Section: An Important Experimental Curve During Progressive Evaporationmentioning

confidence: 99%

“…Whether the d 37 Cl value of seawater decreased over the evaporation process with progressive evaporation? These questions were points addressed in Luo et al (2012Luo et al ( , 2014, in Luo et al (2014) we also constructed the chlorine isotopic evolution curves during seawater evaporation as curves in Eggenkamp et al (1995) based on these fractionation factors.…”

Section: Introductionmentioning

confidence: 99%

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Luo

Wen

et al. 2015

Applied Geochemistry

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Section: Analytical Techniques Have No Influence On Determination Thesupporting

confidence: 93%

Section: Introductioncontrasting

confidence: 60%

Section: Introductionmentioning

confidence: 79%

Section: An Important Experimental Curve During Progressive Evaporationmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Reply to the comment on the paper “Stable isotope fractionation of chlorine during the precipitation of single chloride minerals”

Luo

Wen

et al. 2015

Applied Geochemistry

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Mass Spectrometry‐based Techniques for Direct Quantification of High Ionization Energy Elements in Solid Materials—challenges and Perspectives

Gubal

Chuchina

Sorokina

et al. 2020

Mass Spectrometry Reviews

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The determination of nonmetals, first of all, the most electronegative ones—nitrogen, oxygen, fluorine, chlorine, and bromine, poses the highest challenge for element analysis. These elements are characterized by high reactivity, volatility, high ionization energy, and the absence of intensive spectral lines in the optical spectral range. Conventional techniques of their quantification include considerable “wet chemistry” stages so the application of these techniques for the solid sample is highly laborious and prone to uncontrollable uncertainties. Additionally, current development in material science and other areas requires the quantification of the elements at lower levels with good sensitivity. Owing to their robustness and flexibility, mass spectrometry techniques provide vast possibilities for the quantification, spatial and isotopic analysis, including the solutions for direct analysis of solids. The current review focuses on the application of major mass spectrometric techniques for the quantification of N, O, F, Cl, and Br in solid samples. The following techniques are mainly considered: thermal ionization mass spectrometry (TIMS), isotope‐ratio MS (IRMS), secondary ion MS (SIMS), inductively coupled plasma MS (ICP‐MS), and glow discharge MS (GDMS); as the most accessible and widely applied for the purpose. General ionization issues, advantages, limitations, and novel methodological solutions are discussed. © 2020 John Wiley & Sons Ltd.

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Halogen Elements in Sedimentary Systems and Their Evolution During Diagenesis

Worden

2018

Springer Geochemistry

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Stable isotope fractionation of chlorine during the precipitation of single chloride minerals

Cited by 37 publications

References 33 publications

Reply to the comment on the paper “Stable isotope fractionation of chlorine during the precipitation of single chloride minerals”

Reply to the comment on the paper “Stable isotope fractionation of chlorine during the precipitation of single chloride minerals”

Mass Spectrometry‐based Techniques for Direct Quantification of High Ionization Energy Elements in Solid Materials—challenges and Perspectives

Halogen Elements in Sedimentary Systems and Their Evolution During Diagenesis

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