“…S2 in Supporting Information shows the section of the IR spectrum of PbBa 2 (B 3 O 6 ) 2 from 400 to 4000 cm À1 . The IR spectrum of the synthetic samples exhibits the following absorptions which are assigned referring to literatures [28][29][30]. The main IR absorption region between about 1100 and 1400 cm À1 reveals several absorption bands owing to asymmetric stretching of trigonal BO 3 (1320 and 1216 cm À1 ) groups.…”
“…S2 in Supporting Information shows the section of the IR spectrum of PbBa 2 (B 3 O 6 ) 2 from 400 to 4000 cm À1 . The IR spectrum of the synthetic samples exhibits the following absorptions which are assigned referring to literatures [28][29][30]. The main IR absorption region between about 1100 and 1400 cm À1 reveals several absorption bands owing to asymmetric stretching of trigonal BO 3 (1320 and 1216 cm À1 ) groups.…”
“…S11 †). 44,45 The similar IR spectrum shapes of L4RBO and L4CBO further testify that the two crystals are isomorphic and share the same BO groups. As shown in Fig.…”
Section: Structure and Properties Of The Newly Synthesized LI 4 Rb 3 ...mentioning
Exploration on the compounds in the complex alkali metal borate system had resulted in the discovery of a class of deep-ultraviolet second-order nonlinear optical (NLO) materials LinMn−1B2n−1O4n−2 (M = Cs/Rb, n = 3, 4, 6).
“…The 1030 cm -1 band are likely the asymmetric and symmetric stretching of B-O in BO 4 . The deformation vibration at 918 and 687 cm -1 can be assigned as the bending of BO 3 groups [19,[23][24][25][26][27][28]. …”
A novel borate compound with the chemical formula Mg 2 Na 2 ZnB 4 O 10 (MNZB) has been synthesized first time from the 2MgO-Na 2 O-ZnO-2B 2 O 3 system via solid-state reaction. The obtained polycrystalline borate material MNZB was characterized by powder X-ray diffraction, Fourier transform infrared (FT-IR) spectroscopy, and second harmonic generation (SHG) measurement. Ultraviolet-visible spectroscopy has been carried out to analyze transmission of the MNZB crystals grown by slow cooling method. The optical band gap has been estimated. The functional groups were identified by using the FT-IR data. The SHG efficiency of the crystal was obtained by the Kurtz powder technique and it is found to be 2.78 times that of potassium dihydrogen phosphate. The results are presented and discussed.
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