The digital twin is one of the most promising technologies for realizing smart cities in terms of planning and management. For this purpose, Milan, Italy, has started a project to acquire aerial nadir and oblique images and LiDAR and terrestrial mobile mapping data. The Leica CityMapper-2 hybrid sensor has been used for aerial surveys as it can capture precise and high-resolution multiple data (imagery and LiDAR). The surveying activities are completed, and quality checks are in progress. This paper concerns assessing aerial LiDAR data of a significant part of the metropolitan area, particularly evaluating the accuracy, precision, and congruency between strips and the point density estimation. The analysis has been conducted by exploiting a ground control network of GNSS and terrestrial LiDAR measurements created explicitly for this purpose. The vertical component has an accuracy root mean square error (RMSE) of around 5 cm, and a horizontal component of around 12 cm. Meanwhile, the precision RMSE ranges from 2 to 8 cm. These values are suitable for generating products such as DSM/DTM.