A method for preparing a new polar substituted triazine stationary phase is described. The structure of the triazine phase on silica was characterized by elemental analysis, and by FfIR, solid state Ff_l3C NMR, and 29Si NMR spectral analysis. The chromatographic properties of this packing material have been evaluated by using a number of different solutes, and the properties compared with those of a commercial stationary phase RP-.l8.II is found that this triazine phase has weak z-doaor ligands on the silica surface.