Extensions of fuzzy sets to broader contexts constitute one of the leading areas of research in the context of problems in artificial intelligence. Their aim is to address decision-making problems in the real world whenever obtaining accurate and sufficient data is not a straightforward task. In this way, spherical fuzzy sets were recently introduced as a step beyond to modelize such problems more precisely on the basis of the human nature, thus expanding the space of membership levels, which are defined under imprecise circumstances. The main goal in this study is to apply the spherical fuzzy set version of Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS), a well-established multicriteria decision-making approach, in the context of planetary defense. As of the extraction of knowledge from a group of experts in the field of near-Earth asteroids, they rated four deflection technologies of asteroids (kinetic impactor, ion beam deflection, enhanced gravity tractor, and laser ablation) that had been previously assessed by means of the classical theory of fuzzy series. This way, a comparative study was carried out whose most significant results are the kinetic impactor being the most suitable alternative and the spherical fuzzy set version of the TOPSIS approach behaves more sensitively than the TOPSIS procedure for triangular fuzzy sets with regard to the information provided by our group of experts.