Stereochemistry and crystal structure of diphenyltin dichloride complexes with Meso- or Rac-Bis(phenylsulphinyl)ethane

Bao, Jinting; Shao, Pengcheng; Wang, R.J.; Wang, H.G.; Yao, X.K.

doi:10.1016/0277-5387(94)00312-3

Cited by 6 publications

(5 citation statements)

References 11 publications

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“…The flexible disulfoxide ligands have many intriguing features, such as the bidentate ditopic nature, the inherent chiral properties of the sulfur atom, and the diastereomeric meso and rac forms. They can coordinate to metal ions via either O or S donors according to their electronic and steric factors to form extended structures. − In addition, the configuration inversion of the sulfur atoms in the disulfoxide molecules may take place when reacting with metal ions . As for lanthanide disulfoxide complexes, several polymers with chain or framework structures were reported by us and others. 5d,8c-f These results indicate that the construction of high dimensional lanthanide coordination polymers is possible by selecting suitable disulfoxide ligands as building blocks.…”

Section: Introductionmentioning

confidence: 93%

Novel Lanthanide Coordination Polymers with a Flexible Disulfoxide Ligand, 1,2-Bis(ethylsulfinyl)ethane: Structures, Stereochemistry, and the Influences of Counteranions on the Framework Formations

Lǐ

Zhang

2003

Inorg. Chem.

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The reactions of meso-1,2-bis(ethylsulfinyl)ethane (meso-L) with Ln(ClO(4))(3) [Ln(NO(3))(3) or Ln(NCS)(3)] in MeOH and CHCl(3) gave a series of new lanthanide coordination polymers, [[Ln(micro-meso-L)(rac-L)(2)(CH(3)OH)(2)](ClO(4))(3)](n) [Ln: La (1), Nd (2), Eu (3), Gd (4), Tb (5), Dy (6), and Yb (7)], [Yb(micro-meso-L)(1.5)(NO(3))(3)](n) (8), and [La(micro-meso-L)(2.5)(NCS)(3)](n) (9). All the structures were established by single-crystal X-ray diffraction. Complexes 1-7 are isostructural with infinite single micro-chain structure, in which the L ligands take two kinds of coordination modes: bidentate chelating and bis-monodentate bridging. Six sulfur atoms of the sulfoxide groups around each Ln(III) center adopt alternatively the same R or S configuration in the chain. In addition, the configuration change of partial ligands occurred from the meso to the rac form when reacting with Ln(ClO(4))(3). To our knowledge, this is the first example of disulfoxide complexes with two kinds of coordination modes and three kinds of configurations (R,R, S,S, and R,S) occurring simultaneously in the same complex. 8 exhibits single-double bridging chain structure, in which dinuclear macrometallacycles formed through bridging two Yb(III) by two meso-L ligands are further linked by another meso-L ligand. In 9 each La(III) ion is linked to five other La(III) ions by five meso-L ligands to form a 5-connected 2-D (3/4,5) network containing two types of macrometallacyclic arrays: quadrilateral and triangle grids. The structural differences among 1-7, 8, and 9 show that counteranions play important roles in the framework formation of such coordination polymers. In addition, the luminescent properties of 3 and 5 were also investigated.

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Section: Introductionmentioning

confidence: 93%

Novel Lanthanide Coordination Polymers with a Flexible Disulfoxide Ligand, 1,2-Bis(ethylsulfinyl)ethane: Structures, Stereochemistry, and the Influences of Counteranions on the Framework Formations

Lǐ

Zhang

2003

Inorg. Chem.

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“…In this work, however, when meso ligands react with Cu II ions at room temperature to form complexes, the disulfoxide ligands in the complexes 3B , 2D , and 3D have a rac configuration, indicating that the change of the configuration occurs from a meso to a rac form in the reacting process. In some earlier investigations, 9j, the configurational change of the sulfoxide entities seemed to occur at higher temperature (ca. 70∼80 °C).…”

Section: Resultsmentioning

confidence: 83%

“…This result indicates that a metal-assisted configurational change of the disulfoxide compound may occur even at room temperature. Simultaneously, it is also reported in the literature that the configurational inversion of disulfoxides occurs, more frequently, not from meso to rac but from rac to meso in bis(phenylsulfinyl)alkane complexes,17b This result may be attributed to the difference in stability of the two forms ( meso and rac ), due to the different kinds of disulfoxide ligands. (vi) Finally, all these complexes with O coordination adopt a trans,trans arrangement with the M−O−S−C angle being in the range of 90−270° (see Table ).…”

Section: Resultsmentioning

confidence: 84%

Flexible Disulfoxides as Bridging Ligands for Copper(II) Coordination Architectures: Fine Tuning the Complex Structures by Ligand Modifications

Lǐ

Zhang

et al. 2005

Crystal Growth & Design

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Ten disulfoxide−CuII coordination architectures, {[Cu(meso-L b )2(ClO4)](ClO4)} n (1B), [Cu(meso-L b )2(ClO4)2] n (2B), [Cu(rac-L b )2(ClO4)2] n (3B), {[Cu(meso-L b 3 )3](ClO4)2} n (3B‘), [Cu(meso-L c 1 )2(ClO4)2] n (1C), [Cu(meso-L c 2 )2(ClO4)]2(ClO4)2(CHCl3)2 (2C), {[Cu(meso-L c 3 )2(ClO4)](ClO4)} n (3C), [Cu(meso-L d 1 )2(ClO4)2] n (1D), {[Cu2(rac-L d 2 )4(ClO4)2](ClO4)2(CHCl3)} n (2D), and [Cu(rac-L d 3 )2(ClO4)2] n (3D), were obtained by the reaction of Cu(ClO4)2 with nine structurally related flexible disulfoxide ligands, RS(O)(CH2) n S(O)R (n = 2−4; R = −CH2CH3, −CH2CH2CH3, −CH2CH2CH2CH3 for L b n - 1 , L c n - 1 , and L d n - 1 , respectively) in the presence of dehydrating reagent (diethoxyethane) in acetone/chloroform. The X-ray crystal structural analyses of the complexes revealed that all of them display a 2-D network structure, except for 2B and 2C, which display a one-dimensional and a dinuclear cage structure, respectively. All 2-D systems have a (4,4) topological arrangement with different conformations, except for 3B‘, which has a (3,6) structure. It is noteworthy that complexes 3B and 3B‘, with different structures, are obtained in the same reaction system, being a relatively rare case. In all of the complexes the ligands react in the bis-monodentate coordination mode, acting as linkage bridges: this feature is important for the assembly of the polymeric complexes. In addition, the configuration inversion of some disulfoxide ligands has been observed when reacting with CuII ions. In combination with other reported disulfoxide−CuII complexes, a systematic structural comparison was performed so as to summarize some general relationships among the spacer lengths, terminal groups of related ligands, and structures of the complexes. The magnetic behavior of three complexes, 1B−3B, as examples, was investigated.

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“…For background to organotin compounds, see: Davies et al (2008); Tian et al (2005). For related structures, see: Sadiq-ur-Rehman et al (2007); Ng & Rheingold (1989); Bao et al (1995); Dang (2009); Sousa et al (2009); Yu et al (1992).…”

Section: Related Literaturementioning

confidence: 99%

“…Several structures of organotin sulfoxide complexes, such as dichloridobis(dimethylsulfoxide-κO)diphenyltin (Sadiq-ur-Rehman et al, 2007), dichloridodimethyl(dibenzylsulfoxide-κO)tin (Ng & Rheingold, 1989), [bis(phenylsulfinyl)ethane-κO,O′]dichloridodiphenyltin (Bao et al, 1995), bis(benzylphenylsulfoxide-κO)dichloridodiphenyltin (Dang, 2009) or dibutyldichloro(2-phenyl-1,3-dithiane-1,3-dioxide-κO)tin (Sousa et al, 2009), have been reported. As a continuation of these studies, the structure of the title compound, (I), is described here.…”

Section: S1 Commentmentioning

confidence: 99%

(Benzyl phenyl sulfoxide-κO)dichloridodiphenyltin(IV)

Tan

Zhang²,

Liu

2011

Acta Cryst E

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Stereochemistry and crystal structure of diphenyltin dichloride complexes with Meso- or Rac-Bis(phenylsulphinyl)ethane

Cited by 6 publications

References 11 publications

Novel Lanthanide Coordination Polymers with a Flexible Disulfoxide Ligand, 1,2-Bis(ethylsulfinyl)ethane: Structures, Stereochemistry, and the Influences of Counteranions on the Framework Formations

Novel Lanthanide Coordination Polymers with a Flexible Disulfoxide Ligand, 1,2-Bis(ethylsulfinyl)ethane: Structures, Stereochemistry, and the Influences of Counteranions on the Framework Formations

Flexible Disulfoxides as Bridging Ligands for Copper(II) Coordination Architectures: Fine Tuning the Complex Structures by Ligand Modifications

(Benzyl phenyl sulfoxide-κO)dichloridodiphenyltin(IV)

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