2023
DOI: 10.1002/anie.202311669
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StereoPHIP: Stereoselective Parahydrogen‐Induced Polarization

Mai T. Huynh,
Emily Buchanan,
Sara Chirayil
et al.

Abstract: Parahydrogen induced polarization (PHIP) followed by polarization transfer to 13C is a rapidly developing technique for the generation of 13C hyperpolarized substrates. Chirality plays an essential role in living systems and differential metabolism of enantiomeric pairs of metabolic substrates is well documented. Inspired by asymmetric hydrogenation, here we report stereoPHIP, which involves the addition of parahydrogen to a prochiral substrate with a chiral catalyst followed by polarization transfer to 13C sp… Show more

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