As a trial to realize kink band strengthening in titanium alloys, slight cold rolling followed by aging heat treatment were applied on Ti12 mass% Mo alloys for obtaining mille-feuille-like layered hcp (¡)/bcc (¢) two phase structure. After slight cold rolling at rolling reduction of 5% and subsequent aging heat treatment at 973 K for 180 ks, plate-like ¡ phases were precipitated in the ¢ phase matrix and made an alternately stacked mille-feuille-like ¡/¢ layered structure. These ¡ phases were precipitated on the boundary of {3 3 2}©1 1 3ª ¢ type deformed twins introduced in the ¢ phase matrix during the slight cold rolling. The thin film-like ¡ phase precipitated at a very early stage of aging, and became thicker during aging to produce the mille-feuille-like ¡/¢ layered structure.