1998
DOI: 10.1557/jmr.1998.0272
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Stress evolution in passivated thin films of Cu on silica substrates

Abstract: Stresses supported by thin films of Cu passivated by SiO x have been measured upon thermal cycling. Very high stresses have been found, approaching 1 GPa in the thinnest (40 nm) films. Strengthening beyond yield occurs upon both cooling and heating, indicative of strong strain hardening in the Cu. The hardening continues down to at least 77 K. The yielding behavior of the Cu films has been characterized by a kinematic constitutive law, with exceptional strain hardening and a conventional temperature-dependent … Show more

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Cited by 56 publications
(10 citation statements)
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“…Moreover, conventional theory predicts there is no eect of a very thin passivation layer deposited on top of the free surface. Passivation layers are known to signi®cantly increase the stress changes when the ®lm deforms plastically (Shen et al, 1998). The physical situation at the free surface and the interface are quite dierent.…”
Section: Is a Higher Order Theory Necessary?mentioning
confidence: 99%
“…Moreover, conventional theory predicts there is no eect of a very thin passivation layer deposited on top of the free surface. Passivation layers are known to signi®cantly increase the stress changes when the ®lm deforms plastically (Shen et al, 1998). The physical situation at the free surface and the interface are quite dierent.…”
Section: Is a Higher Order Theory Necessary?mentioning
confidence: 99%
“…Accordingly, much attention has been directed to experimentally characterizing the mechanical properties of thin films by a variety of techniques, e.g. (Vlassak and Nix, 1992;Shen et al, 1998;Hommel and Kraft, 2001;Espinosa et al, 2003Espinosa et al, , 2004Dehm et al, 2003;Lou et al, 2003;Phillips et al, 2004;Florando and Nix, 2005;Xiang et al, 2005), and to modeling their size-dependent behavior, e.g (Hutchinson, 2001;Haque and Saif, 2003;Pant et al, 2003;Groh et al, 2003;Von Blanckenhagen et al, 2004;Ghoniem and Han, 2005;Hartmaier et al, 2005;Nicola et al, 2003Nicola et al, , 2005a. Additional references can be found in the works cited.…”
Section: Introductionmentioning
confidence: 99%
“…Much attention has been paid to the thermomechanical response of thin Cu films in recent years. [1][2][3][4][5][6][7][8][9][10][11][12][13] Passivated (encapsulated) Cu films behave differently from their unpassivated counterparts, a feature in contrast with that of Al films, which are mechanically insensitive to artificial passivation (even the unpassivated Al film is inherently coated with a thin layer of native oxide). Mechanical stresses in a passivated Cu film, generated from the thermal mismatch with the substrate, do not relax significantly at elevated temperatures during temperature cycling.…”
Section: Introductionmentioning
confidence: 99%