Tribological behaviour of undoped DLC (diamond‐like carbon) and titanium‐doped DLC coatings, referred here as TiC:H, were investigated. Tribological properties of frictional contacts with DLC coating significantly depend on the type of counterpart and generally are conditioned on the processes of abrasive wear, and the oxidation of counterpart and coating, and to smaller extent on the process of coating graphitisation. On the other hand, tribological properties of frictional contacts with TiC:H coating are mainly conditioned on the processes of graphitisation and coating oxidation, which already at the initial stage leads to the formation of a stable transfer layer consisting mainly of graphite‐like carbon and titanium oxides, i.e. products of low shear strength playing the part of a solid lubricant.