This work is aimed at investigating the viability of
utilizing
cadmium sulfide (CdS) as a buffer layer in CdTe solar cells by analyzing
and assessing its optical, photoluminescence, morphological, and electrical
properties. These films were fabricated using a thermal coating technique.
Optical microscopy was used to observe the changes in morphology resulting
from the doping of rare-earth metals such as samarium (Sm) and lanthanum
(La) to CdS, while the granular-like structure of the sample was confirmed
by scanning electron microscopy. The objective of incorporating Sm
and La ions into CdS was to enhance photoconductivity and optimize
the optical bandgap, aiming to create a viable charge transport material
for photovoltaic devices with enhanced efficiency. Through that process,
a noticeable decrease in transmission, from approximately 80 to 68%
in the visible region, was observed. Additionally, the bandgap value
was reduced from 2.43 to 2.27 eV. Furthermore, during the analysis
of the photoluminescence spectra, it was observed that emission peaks
occurred in the visible region. These emissions were attributed to
electronic transitions that took place via band-to-band and band-to-impurity
interactions. The electrical measurements showed an enhancement in
conductivity due to the decrease in the bandgap. This notable consequence
of the doped materials suggests their utilization in photovoltaic
systems.