Undoped and Sb-doped SnO 2 nanofibers were prepared by electrospinning and their responses to H 2 , CO, CH 4 , C 3 H 8 , and C 2 H 5 OH were measured. In the undoped SnO 2 nanofibers, the gas response (R a /R g , R a : resistance in air, R g : resistance in gas) to 100 ppm C 2 H 5 OH was very high(33.9), while that to the other gases ranged from 1.6 to 2.2. By doping with 2.65 wt% Sb, the response to 100 ppm C 2 H 5 OH was decreased to 4.5, whereas the response to H 2 was increased to 3.0. This demonstrates the possibility of detecting a high H 2 concentration with minimum interference from C 2 H 5 OH and the potential to control the gas selectivity by Sb doping.