2001
DOI: 10.1063/1.1345819
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Structural changes during annealing of GaInAsN

Abstract: The alloy GaInAsN has great potential as a lower-band-gap material lattice matched to GaAs, but there is little understanding of what causes its poor optoelectronic properties and why these improve with annealing. This study provides information about the structural changes that occur when GaInAsN is annealed. The Fourier transform infrared spectra exhibit two primary features: a triplet at ∼470 cm−1 (Ga–N stretch) and two or three bands at ∼3100 cm−1 (N–H stretch). The change in the Ga–N stretch absorption ca… Show more

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Cited by 236 publications
(168 citation statements)
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“…The formation of this In−N cluster reduces the strain in the alloy [21]. Therefore this could be a reason for the blue shift of PL peak position after annealing.…”
Section: Resultsmentioning
confidence: 99%
“…The formation of this In−N cluster reduces the strain in the alloy [21]. Therefore this could be a reason for the blue shift of PL peak position after annealing.…”
Section: Resultsmentioning
confidence: 99%
“…The In-concentration of the layers measured separately by X-ray microanalyses is 6.4%. Using Vegard's law the N-content in InGaAsN layers is determined to be 2.8% (Mintairov et al, 2001, Hashimoto et al, 2003 and for some MBE and MOCVD samples after annealing (Pavelescu et al,2005;Kurtz et al 2001). The experimentally observed local modes could be explained by theoretical analyses of the microscopic lattice structures related to the incorporation of N in InGaAsN alloys.…”
Section: Structural Characterizationmentioning
confidence: 92%
“…The thermal annealing of In x Ga 1-x N y As 1-y epitaxial films at 670 C-700 C during 15-30 min is an efficient method to change the arrangement of In and nitrogen atoms over long distances. 15,16 B x In 1-x Bi y B V 1-y belong to the same type of alloy just as In x Ga 1-x N y As 1-y . That is why the temperature range from 0 C to 800 C was chosen for the calculations.…”
Section: Resultsmentioning
confidence: 99%