Structural investigation of tin(IV) alkoxide compounds—II. Solid state and solution structural characterization of [Sn(O-i-Bu)4· HO-i-Bu]2

New Fluorinated Stannic Compounds as Precursors of F-Doped SnO2 Materials Prepared by the Sol−Gel Route

“…Tetra( tert -amyloxy)tin(IV) was synthesized according to Thomas's procedure . Trans-alcoholysis of the latter compound gave tetra(isopropoxy)tin(IV) and tetra(ethoxy)tin(IV) according to previously reported results …”

Deposition of tin sulfide thin films from tin(iv) thiolate precursors

“…The coordination about tin is, perhaps not surprisingly, tetrahedral, in contrast to the corresponding (RO) 4 Sn species which, having higher Lewis acidity due to the more polar Sn± O bonds, expand their coordination spheres by dimerisation (m-OR bridged) and/or solvation by ROH. 43,44 The structure of [MeS(Ph)CLC(Ph)S] 4 Sn, which incorporates a ligand predisposed to chelation, does however show two sets of Sn±S bonds corresponding to the strong covalent [2.436(1) A Ê ] and weaker coordinate [3.599(2) A Ê ] Sn±S interactions. 42 The Sn±S bonds in 46 and [MeS(Ph)CLC(Ph)S] 4 Sn.…”

Bis(μ-propan-2-olato-κ2O:O)bis[chlorido(propan-2-ol-κO)bis(propan-1-olato-κO)tin(IV)]

“…(Sterr & Mattes, 1963) and Et (Genge et al, 1996;Webster & Collins, 1974)], SnCl 3 (OCH 3 ).2CH 3 OH (Reuter & Schröder, 1992), Sn(O i Pr) 4 . i PrOH (Hampden-Smith et al, 1991;Reuter & Kremser, 1991), SnCl(O i Bu) 3 .HO i Bu (Reuter & Kremser, 1993), Sn(O i Bu) 4 .HO i Bu (Chandler et al, 1995) and Sn 2 (CH 3 O) 2 Cl 6 (C 3 H 7 NO) 2 (Zhang et al, 2011). In all these cases, two octahedrally coordinated Sn atoms are bridged by two µ-OR groups.…”

“…For the synthesis of the title compound, see: Mehrotra & Gupta (1966). For related structures, see: Chandler et al (1995); Genge et al (1996); Hampden-Smith et al (1991); Reuter & Kremser (1991, 1993; Reuter & Schrö der (1992); Sterr & Mattes (1963); Webster & Collins (1974); Zhang et al (2011). For alcohol adducts of alkoxides, see: Vaartstra et al (1990).…”