“…The approximated band gap is; however, smaller than that of the bulk ZnTe (2.26 eV). The observed reduction in the energy band gap could be attributed to the surface defects density of undoped ZnTe [24,42].The slope of the different samples prepared varied due to the non-uniformity in particle sizes as confirmed by HRTEM analysis.The E values for the ZnTe nanoparticles were calculated by extrapolating the linear portion of the (khv) 2 verses hv curves to the hv axis (Figure 12). The E values for ZnTe prepared at 15, 30, 60, 180, 300 and 420 minutes were 2.27, 2.20, 2.19, 2.17, 2.16 and 2.01 eV respectively.…”