The results of using a hybrid technology for the synthesis of ultrafine carbon powder material in an amorphous state are considered. Different modes of hybrid technology are proposed, including mechanochemical synthesis in a ball mill and the process of self-propagating sustainable combustion in a natural atmosphere to produce carbon powder materials (CPM) in an amorphous state. Using X-ray diffraction methods: diffractometric, radiographic, and small-angle X-ray scattering, heterogeneities of the CPM structure were studied. Areas of structural heterogeneity having a flat shape and containing up to 10 graphene-like layers are revealed.