2011
DOI: 10.1039/c1ce05581j
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Structural phase transition due to the flexible supramolecule of (4-cyanomethylanilinium)([18]crown-6) in [Ni(dmit)2]− crystal

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Cited by 20 publications
(6 citation statements)
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“…7 For the [Ni(dmit) 2 ] 2 salt with (4-cyanomethylanilinium) [18]crown-6, the rotation or motion of phenyl ring and cyanomethyl group is associated with the structural phase transition at 153 K, at which temperature the space group was changed from centric Pbcn (high-temperature phase) to chiral P2 1 2 1 2 1 (low-temperature phase). 8 As a continuation of our work on molecular machines with rotator or molecular motion, herein we report a new phase transition [Ni(dmit) 2 ] 2 salt with (4-ethoxyanilinium) [18]crown-6 supramolecular cation (Scheme 1) and its dielectric and piezoelectric properties.…”
Section: Introductionmentioning
confidence: 90%
“…7 For the [Ni(dmit) 2 ] 2 salt with (4-cyanomethylanilinium) [18]crown-6, the rotation or motion of phenyl ring and cyanomethyl group is associated with the structural phase transition at 153 K, at which temperature the space group was changed from centric Pbcn (high-temperature phase) to chiral P2 1 2 1 2 1 (low-temperature phase). 8 As a continuation of our work on molecular machines with rotator or molecular motion, herein we report a new phase transition [Ni(dmit) 2 ] 2 salt with (4-ethoxyanilinium) [18]crown-6 supramolecular cation (Scheme 1) and its dielectric and piezoelectric properties.…”
Section: Introductionmentioning
confidence: 90%
“…Knowledge of financial literacy is very important for an individual, so that they are not wrong in making their financial decisions. The lacking knowledge of financial literacy, resulting in losses for individuals, either as a result of inflation, a decline in economic conditions both domestically and abroad, or the development system [7]. Hypothesis is a temporary answer or conclusion/is still a presumption that must be tested with the data that has been collected to give directives to the study in accordance with what was expected.…”
Section: Theoretical and Frameworkmentioning
confidence: 99%
“…Moreover, the introduction of molecular motions to solid state material is one of the effective methods to construct the orderdisorder type phase transition compounds [16][17][18][19][20][21]. Generally, plastic crystalline states such as hexamethylethane, cyclohexane, adamantane, and fullerene (C60), whose structures are flexible, have a tendency to lead to the phase transition triggered by temperature [22][23][24][25]. Among them, cyclohexane and long-chain amine with flexible structure and complicated conformation will be the good candidate group to construct the phase transition compound.…”
Section: Introductionmentioning
confidence: 99%