2005
DOI: 10.1016/j.crci.2005.03.003
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Structural variation in the copper(II) complexes with a tetradentate bis-6-methylpyridine-substituted bispidine ligand

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Cited by 16 publications
(36 citation statements)
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“…This was achieved by tuning the reduction potential on the basis of subtle structural modifications, which enforce a stabilization of the less-common "Jahn-Teller isomers". [36][37][38] Both experimental and DFT-based results indicate that the reduction of the copper(II) precursors is an inner-sphere process to yield a catalytically active copper nitrene species. In contrast with earlier results, [30] there is no significant difference between complexes of tetra-and pentadentate bispidine ligands.…”
Section: Resultsmentioning
confidence: 97%
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“…This was achieved by tuning the reduction potential on the basis of subtle structural modifications, which enforce a stabilization of the less-common "Jahn-Teller isomers". [36][37][38] Both experimental and DFT-based results indicate that the reduction of the copper(II) precursors is an inner-sphere process to yield a catalytically active copper nitrene species. In contrast with earlier results, [30] there is no significant difference between complexes of tetra-and pentadentate bispidine ligands.…”
Section: Resultsmentioning
confidence: 97%
“…[36] Although there still is the usual elongation along N7ÀCu with the "sterically innocent" monoA C H T U N G T R E N N U N G dentate co-ligand acetonitrile in combination with the methylated ligand L 5 or the less sterically demanding quinoline donors in L 6 , larger co-ligands such as Cl À ions lead to a partially quenched Jahn-Teller elongation along N3 À Cu and, with the chelating NO 3 À ions, longer bonds to the aromatic donors are observed with L 5 . With the large Br substituents of L 7 , the latter type of structure is already observed with acetonitrile as the co-ligand.…”
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confidence: 97%
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