Structure and physical properties of aluminium alkoxides. Part IV: Vapour pressures of aluminium isopropoxide

Abstract

The vapour pressure of aluminium isopropoxide is measured statically at temperatures ranging from 80" to 126". In the lower part of this range the compound is more volatile than is indicated by previous data. For the latent heat of vaporization a value of I 1.5 f 1.5 kcal/mole is calculated. This low value points to just small shifts in degree of association upon vaporization.

CVD‐Fabricated Aluminum Oxide Coatings from Aluminum tri‐iso‐propoxide: Correlation Between Processing Conditions and Composition

“…ATI (Acros Organics), a nontoxic powder, was melted above 413 K and then was kept supercooled at 353 K. During deposition, ATI was heated at 383 K. At this temperature, its saturated vapor pressure is between 97 Pa and 285 Pa depending on the literature source [56][57][58]. Because of structural evolution upon ageing, the precursor was renewed in the bubbler after nearly 12 h of use.…”

Corrosion protection of 304L stainless steel by chemical vapor deposited alumina coatings

“…Processing conditions were the same in all experiments: deposition temperature and pressure 480°C and 0.67 kPa, respectively, bubbling 20 standard cubic centimetres per minute (sccm) 99.9992% pure N 2 (Air Products) flow through liquid ATI maintained at 383 K and further diluting the gas phase with additional 631 sccm N 2 . These conditions lead to a theoretical flow rate of ATI between 4 and 7 sccm [20], depending on the adopted law for ATI vapor pressure provided in the literature [21][22][23]. The resulting growth rate of the coating was around ca.…”

Aluminium tri-iso-propoxide: Shelf life, transport properties, and decomposition kinetics for the low temperature processing of aluminium oxide-based coatings

“…Several authors have measured ATI vapour pressure against temperature [18][19][20]. Sladek et Gibert [21] and Morssinkhoff [17] used results from references [6,22].…”

“…2. Clausius-Clapeyron plots of ATI vapour pressure from various studies: open squares [6,17,21-23], dark circles[18], open circles[19], open triangles[20]; dark triangles correspond to the present study.…”