Structure and Solid Hydrolysis of 3, 1-Benzoxazin-4-Ones

Vicens, Jacques; Décoret, C.; Gaget, C.; Etter, Margareth C.; ERREDE, L. A.

doi:10.1080/00268948308074689

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Solid State Hydrolysis of 2‐Methyl‐4H‐benzoxazin‐4‐one. Mode of Propagation of the Reaction Process During the Hydrolysis

Vicens

Décoret

Royer

et al. 1985

Israel Journal of Chemistry

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Kinetic studies of hydrolysis and deuteriolysis of microcrystalline 2‐methyl‐4H‐benzoaxazin‐4‐one 1 into N‐acetylanthranilic acid 2 are presented. Hydrolysis of mixtures of microcyrstalline 1 and 2 are given. The results are interpreted and a mechanism is proposed for the solid gas reaction. A theoretical approach of the crystal packing of 1 permits an evaluation of the mode of diffusion of water molecules in the crystal. Both experimental and theoretical results lead to a proposal of the mechanism of water propagation and the hydrolysis process in the solid phase.

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