Structure and tribological properties of Si/a-C:H(Ag) multilayer film in stimulated body fluid*

Abstract

Si/a-C:H(Ag) multilayer films with different modulation periods are prepared to test their potential applications in human body. The composition, microstructure, mechanical and tribological properties in the simulated body fluid are investigated. The results show the concentration of Ag first decreases and then increases with the modulation period decreasing from 984 nm to 250 nm. Whereas the C content has an opposite variation trend. Notably, the concentration of Ag plays a more important role than the modulation period in the properties of the multilayer film. The a-C:H sublayer of the film with an appropriate Ag concentration (8.97 at.%) (modulation period of 512 nm) maintains the highest sp3/sp2 ratio, surface roughness and hardness, and excellent tribological property in the stimulated body fluid. An appropriate number of Ag atoms and size of Ag atom allow the Ag atoms to easily enter into the contact interface for load bearing and lubricating. This work proves that the Ag nanoparticles in the a-C:H sublayer plays a more important role in the tribological properties of the composite-multilayer film in stimulated body fluid condition.

Bio-Tribology and Corrosion Behaviors of a Si- and N-Incorporated Diamond-like Carbon Film: A New Class of Protective Film for Ti6Al4V Artificial Implants

“…However, some moving implants, such as joints, serve in environments where corrosion and wear coexist, requiring that the protective film possesses a lubrication effect. It is well-known that diamond-like carbon films are promising protective films with high hardness, low friction coefficient, high chemical inertness, high corrosion resistance, and good biocompatibility. − However, the friction coefficient of a pure hydrogenated amorphous carbon film is close to 0.25 and its wear rate is on the order of 10 –6 mm 3 ·N –1 ·m –1 , which makes it difficult to meet the needs of permanent implants. , Element doping is a recognized method of improving the tribological properties and corrosion resistance of DLC films. − Nevertheless, the introduction of different doping elements is bound to change the physical and chemical properties of the DLC film surface, thus affecting its biocompatibility. For example, F&H-DLC has been reported to exhibit strong antibacterial properties .…”