1984
DOI: 10.1107/s0108270184009768
|View full text |Cite
|
Sign up to set email alerts
|

Structure of bis[N,N-bis(2-hydroxyethyl)dithiocarbamato]nickel(II), C10H20N2NiO4S4

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

1
3
0

Year Published

1988
1988
2012
2012

Publication Types

Select...
7

Relationship

2
5

Authors

Journals

citations
Cited by 12 publications
(4 citation statements)
references
References 2 publications
1
3
0
Order By: Relevance
“…The thioureide CϪN distance is 1.304(3) Å , which is lower than the distance 1.33(1) Å observed in the parent [Ni(dedtc) 2 ][24]. Similar trend was observed in [Ni(dedtc)(PPh 3 ) 2 ] ϩ[20] and in [NiCl(dedtc)(PPh 3 )][16]. Other bond parameters of the dithiocarbamate moiety are normal.…”
supporting
confidence: 53%
“…The thioureide CϪN distance is 1.304(3) Å , which is lower than the distance 1.33(1) Å observed in the parent [Ni(dedtc) 2 ][24]. Similar trend was observed in [Ni(dedtc)(PPh 3 ) 2 ] ϩ[20] and in [NiCl(dedtc)(PPh 3 )][16]. Other bond parameters of the dithiocarbamate moiety are normal.…”
supporting
confidence: 53%
“…Cyclic dithiocarbamates (1, R ¼ alkyl aryl, etc.) have been previously reported, but usually their formation requires more stringent conditions, e.g., on heating or in the presence of acids [18][19][20], especially with specific reagents [21].…”
Section: Introductionmentioning
confidence: 99%
“…Several X-ray crystallographic structural determinations of Ni I~ and Cu I1 dithiocarbamates have been reported in recent years. Thus structures of [Ni(R~R2dtc) 2] with Rl=R2=CH3 (Peyronel & Pegnedoli, 1967), R~ = R 2 = H (Gasparri, Nardelli & Villa, 1967), R~ =-R 2 = C2H 5 (Coucouvanis, 1979), R~ = R 2 = C2H4OH (Ramalingam, Radha, Aravamudan, Mahadevan, Subrahmanyam & Seshasayee, 1984), R~ = CH 3, R 2 = C6H 5 (Martin, Newman, Robinson & White, 1972), R~R2=(CH2) 4 (Raston & White, 1974), R ~R 2 = (cn2) 6 (Agre, Shugan & Rukhadze, 1968) and of [Cu(RlR2dtc) 21 with Rl=R2=CH 3 (Einstein & Field, 1974), RI=R 2 = C4H 9 (Boyd, Mitra, Raston, Rowbottom & White, 1981), R~R2=(CH2) 4 (Newman, Raston & White, 1973), R~=CH 3, R 2=C6H 5 (Martin, Newman, Robinson & White, 1972), R~=R 2=C2H4OH (Radha, Seshasayee, Radha, Aravamudan & Subrahmanyam, 1985) have been determined. The dtc ligand in most of its complexes with transition-metal ions adopts a delocalized form.…”
mentioning
confidence: 99%