Structure of Di-μ-formato-bis(phenanthroline)dirhodium dichloride and application of phenanthroline rhodium compounds as hydrogenation catalysts

Synthesis and Characterization of Complexes of Rh(II) with Purines and Pyrimidines

“…The complexes of Rh(II) show a molar conductance of 6-11 ohm -1 cm 2 in 10 -3 M DMSO and indicate that the complexes are non-ionic. The compounds do not show any EPR signal suggesting them to be diamagnetic which is also confirmed by magnetic measurements in accordance with the expected dimeric nature of the rhodium(II) systems 8 . Thus, the complexes are possibly dimeric in nature with the bridging of the acetato group and the formation of Rh-Rh bond.…”

Interaction of [Rh2(O2CCH3)4(H2O)2] and [Rh2(O2CCH(OH)Ph)2(phen)2(H2O)2](O2C‐CH(OH)Ph)2 With Sulfhydryl Compounds and Ceruloplasmin

“…Dimeric rhodium(II) complexes have attracted considerable interest due to their interesting structure and reactivity [1][2][3][4][5][6][7][8][9][10], catalytic properties [1][2][3]5,[11][12][13] and anticancer activity [1][2][3]5,10,[14][15][16][17][18][19]. The structure, reactivity, catalytic properties and cytostatic activity of [4][5][6][7][8][9][10][11][12][13].…”

“…The structure, reactivity, catalytic properties and cytostatic activity of [4][5][6][7][8][9][10][11][12][13]. Rhodium(II) carboxylato complexes belong to the most promising platinum metals compounds having anticancer and biological activity [14][15][16][17][18][19][20][21].…”

Binuclear Rhodium(II) Complexes With Selective Antibacterial Activity

“…Binuclear rhodium(II) tetracarboxylato complexes [Rh2(/-OOCR)4L2] as well as complexes containing two bridging ligands [Rh2X2(/-OOCR)2(N-N)2] and [Rh2(/-OOCR)2(N-N)2L2]2+, where L Lewis base, X halide and N-N 2,2'-bipyridine, 1,10-phenanthroline and their derivatives have aroused considerable interest because of interesting structure and reactivity [1][2][3][4][5][6][7][8][9], catalytic properties 4, 10] and anticancer activity 4, 11 17]. The antitumor activity of Rh2(OOCR)4 complexes intensified studies of their interaction with biomolecules, e.g.…”