1967
DOI: 10.1007/bf00761166
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Structure of internal complex compounds with metal-sulfur bonds

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Cited by 4 publications
(4 citation statements)
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“…Another related class of compounds N -alkyldithiocarbamato [M(S 2 CNHR) 2 ] has potential as precursors. These complexes have received scant attraction because of a perceived lack of stability and expectation of low volatility. Recently, O’Brien et al synthesized a series of complexes of cadmium or zinc with varying alkyl chain lengths [M(S 2 CNHR) 2 ] (M = Cd, Zn; R = ethyl, n butyl, n hexyl, n dodecyl).…”
Section: Precursors For Ii−vi Materialsmentioning
confidence: 99%
“…Another related class of compounds N -alkyldithiocarbamato [M(S 2 CNHR) 2 ] has potential as precursors. These complexes have received scant attraction because of a perceived lack of stability and expectation of low volatility. Recently, O’Brien et al synthesized a series of complexes of cadmium or zinc with varying alkyl chain lengths [M(S 2 CNHR) 2 ] (M = Cd, Zn; R = ethyl, n butyl, n hexyl, n dodecyl).…”
Section: Precursors For Ii−vi Materialsmentioning
confidence: 99%
“…22 Although there exists a substantial body of work on the N,N-dialkyldithiocarbamato complexes of cadmium or zinc as precursors there is very little reported on the closely related N-alkyldithiocarbamato complexes of cadmium or zinc. 23 This fact may be because the complexes are not generally regarded as very stable. Recently, Caudle et al reported the preparation of some N-alkyldithiocabamato complexes of cadmium(II) and discussed mechanisms for the C-S bond cleavage.…”
Section: Introductionmentioning
confidence: 99%
“…In fact, only one example of a structurally or chemically characterized N-alkyldithiocarbamato derivative of cadmium(II) could be located. 7 This may arise in part from the fact that such complexes are predicted to be considerably less volatile, and thus not suitable as single-source CVD precursors. However, it may also arise from different chemical reactivity of the N-alkyldithiocarbamato species, which makes them less stable than their N,Ndialkylated counterparts.…”
Section: Introductionmentioning
confidence: 99%
“…Given this extensive body of literature on N , N -dialkyldithiocarbamato complexes of Cd 2+ and Zn 2+ , it is surprising to find a substantial void concerning N -alkyldithiocarbamato complexes of group 12 ions. In fact, only one example of a structurally or chemically characterized N -alkyldithiocarbamato derivative of cadmium(II) could be located . This may arise in part from the fact that such complexes are predicted to be considerably less volatile, and thus not suitable as single-source CVD precursors.…”
Section: Introductionmentioning
confidence: 99%