The effect of electroslag remelting (ESR) with CaF 2 -based synthetic slag on the microstructure and mechanical properties of three as-quenched martensitic/martensitic-bainitic ultrahigh-strength steels with tensile strengths in the range of 1250-2000 MPa was investigated. Ingots were produced both without ESR, using induction furnace melting and casting, and with subsequent ESR. The cast ingots were forged at temperatures between 1100 and 950 • C and air cooled. Final microstructures were investigated using laser scanning confocal microscopy, field emission scanning electron microscopy, electron backscatter diffraction, electron probe microanalysis, X-ray diffraction, color etching, and micro-hardness measurements. Mechanical properties were investigated through measurement of hardness, tensile properties and Charpy-V impact toughness. The microstructures of the investigated steels were mainly auto-tempered martensite in addition to small fractions of retained austenite and bainite. Due to the consequences of subtle modifications in chemical composition, ESR had a considerable impact on the final microstructural features: Prior austenite grain, effective martensite grain, and lath sizes were refined by up to 52%, 38%, and 28%, respectively. Moreover, the 95th percentiles in the cumulative size distribution of the precipitates decreased by up to 18%. However, ESR had little, if any, the effect on microsegregation. The variable effects of ESR on mechanical properties and how they depend on the initial steel composition are discussed.The prior austenite grains are divided into packets, which consist of blocks of laths with the same habit plane. These blocks contain sub-blocks in which the laths have similar crystal orientations. The boundaries between packets and blocks have high-angle misorientations while the boundaries between sub-blocks and laths have low-angle misorientations [8][9][10].Strength and toughness properties can be improved simultaneously by grain refining, which can be achieved, for example, by the pinning of the austenite grain boundaries by fine precipitates, which are stable at high temperatures [11]. A high number density of fine precipitates leads to enhanced pinning of the grain boundaries, which subsequently leads to a reduction of the final prior austenite grain, packet, and block sizes and a significant effect on the mechanical properties of the steel. It was observed by Wang et al. [12] that the yield strength of 17CrNiMo6 martensitic steel is increased by 235 MPa by reducing the prior austenite grain size (PAGS) by 33% and the Charpy U-notch impact energy at 77 K was enhanced more than eight-fold.In addition to the above strengthening factors, additional strengthening can be achieved through precipitation. In the case of dislocation bowing between precipitates, the Orowan relationship [13] shows that the yield strength increment from precipitation increases with increasing volume fraction and decreasing size of the precipitates. In the case of tempered martensite, the optimum combinati...